Pablo Carrenobusta

The world number one lost 6-4 6-7 (6-8) 6-3 to Pablo Carreno Busta in the singles bronze medal match, smashing one racket against a net post and tossing another into the stands in gestures of frustration.

Djokovic then cited a shoulder injury as he pulled out of the mixed doubles third-place match. That decision meant Ash Barty and John Peers of Australia took bronze, with Djokovic and his unfortunate Serbia partner Nina Stojanovic finishing fourth.

"I am dealing with injuries. Not one, more than one," Djokovic said in an interview with Serbian media, according to tennismajors.com. "I hope that it won't stop me from going to the US Open, which is my next big goal.

"I feel bad for Nina because we did not fight for a medal in mixed, but my body said 'enough'. I have played under medications and abnormal pain and exhaustion."

The 34-year-old Djokovic said he had put his "very last source of energy" into the tournament and was satisfied with his effort, with a semi-final defeat to Alexander Zverev on Friday having left him resigned to a battle for what by his standards was perceived as a consolation prize.

But Djokovic added: "I know I've not played well today, and yesterday in the second and third set.

"The exhaustion, both physical and mental, got to me and it's unfortunate that in the most important matches I just didn't deliver, but I gave it all."

Djokovic suggested the Paris Olympics in 2024 were a possible target, although he must be becoming sick of Olympic tennis by now, having only one bronze to show for four attempts to win gold.

He took bronze in 2008 but lost to Argentina's Juan Martin del Potro both in the third-place match at London 2012 and the first round at Rio 2016.

Now there is more Games agony to digest, as well as a need to reboot ahead of the upcoming North American hardcourt swing and that US Open campaign. His hopes of a calendar Golden Slam are over but a sweep of the grand slams remains a possibility, having already landed the Australian Open, French Open and Wimbledon titles.

"I've had some heart-breaking losses at the Olympics Games," Djokovic said. "I know that those losses have usually made me stronger. I know that I will bounce back. I will try to keep going for the Paris Olympic Games. I will fight for my country to win medals."

Carreno Busta's reaction was thoroughly refreshing, with the Spaniard jubilant to secure a medal.

He said: "This week has been a very harsh week mentally for me. When I saw Novak lost, and I had to play him for this medal, I had my doubts.

"But last night I slept like I haven't slept in Tokyo. I slept for nine hours straight, that was an advantage to me. I came on to the court today knowing Spain was behind me.

"This is even more incredible than winning other tournaments. I've won Davis Cup, I've gone far in other tournaments, but winning an Olympic medal is indescribable. Words fail me, I felt Spain rallying behind me. A bronze medal is a dream come true for me."

The knock-on effort of Djokovic's withdrawal from the mixed doubles meant Barty and Peers added to Australia's medals haul without having to step on court for the third-place play-off.

Barty insisted she and Peers were worthy bronze medallists, saying: "It's incredible. It's unique circumstances and heartbreaking for Team Serbia not to get out on court.

"But for Johnny and I this is a dream come true for us. I feel like we've really deserved this one."

Spain's Pablo Carreno Busta beat the world number one 6-4 6-7 (6-8) 6-3 to finish third in men's singles.

The shock result followed a day on from Djokovic's hopes of a Golden Slam being crushed by defeat to Alexander Zverev in the semi-finals.

In the wake of his singles third-place match setback, Djokovic also pulled out of the mixed doubles bronze match, citing a left shoulder injury.

Having already clinched the Australian Open, French Open and Wimbledon titles, Djokovic was eyeing gold at the Games before heading to the US Open in August, aiming to land the five biggest prizes in tennis in the same season.

That has never been achieved in a calendar year by a man, and Djokovic could not even manage a consolation prize from his singles mission in Japan. How serious his injury is now remains to be seen.

After levelling the singles match by taking the second-set tie-break, Djokovic boiled over in the first game of the decider, firstly when flinging his racket several rows back from the middle of the court after Carreno Busta put away a volley at the net.

Djokovic picked another racket from his bag but petulantly demolished that against a net post after dropping the third game to slide 3-0 behind, receiving a warning from the umpire for that violent outburst.

His anger may have been explained by injury or by his disappointment on Friday, when, as well as losing to Zverev, Djokovic and Serbian team-mate Nina Stojanovic were beaten in the semi-finals of the mixed doubles.

Djokovic would have had one final shot at a medal from his Tokyo trip to come later on Saturday, with the 34-year-old and Stojanovic due to face Ash Barty and John Peers in another match for bronze.

However, shortly after his singles exit, it was announced that Djokovic had pulled out of that match, handing Barty and Peers the medal.

Amid the anger and frustration exhibited on court by Djokovic, it was a banner day for Carreno Busta, as Spain celebrated another tennis medal, having won at least one in eight of the last nine Olympics.

The 30-year-old fell to the court in joy at the end of the two hours and 47 minutes it took him to defeat the world number one, his elation a sharp contrast to the emotions of his beaten opponent.

From a set and a break up, Djokovic dropped a staggering eight games in a row on his way to a 1-6 6-3 6-1 loss.

The 34-year-old Serbian had been unsure about coming to the Games but was swayed by the pride he takes in representing his country and the tantalising opportunity to add a gold medal to a potential clean sweep of the grand slams.

He has already won the Australian Open, French Open and Wimbledon, and will head to the US Open in August as a heavy favourite regardless of this setback.

But this was just not Djokovic's day, despite him making a whirlwind start and dominating until the point he broke to lead 3-2 in the second set. From there, Zverev seized control. 

When Djokovic volleyed into the net to make it 3-3, dropping serve for the first time in the match, it looked like just a minor stumble.

Yet suddenly he was struggling for form and did not win another game until he was already 4-0 behind in the deciding set.

Zverev was playing blindingly brilliant tennis and was proving obdurate too, saving four break points in the second game of the third set.

He clinched victory with a blazing backhand winner, and goes on to face Russian Karen Khachanov in the final.

The result means Djokovic, like Roger Federer, seems fated never to win the Olympic singles gold medal. And it leaves Steffi Graf as the only player to ever win a calendar Golden Slam, having done so in 1988 when she added the Seoul Olympics title to her haul of majors.

Russian Olympic Committee's Khachanov fended off Spain's Pablo Carreno Busta with some ease in the first semi-final, with the world number 25 sweeping to a 6-3 6-3 victory in an hour and 19 minutes.

He won 26 of 28 points on first serve to freeze out Carreno Busta, who had only one break point all match and could not take that opportunity.

"It's just a pure happiness, a pleasure to be here to live those moments, these kind of memories will stay forever," Khachanov said.

Khachanov delivered a rock solid display, with his serve and forehand at their best, barely giving his opponent a sniff of an opportunity as the Moscow-born 25-year-old established a firm grip.

"That's the way I prepared, against every opponent you play a little bit differently," Khachanov said. "The final will be another story, another match, another day. I hope it will be the same."

Carreno Busta, who will face Djokovic for the bronze medal, said: "It was not the best match I have played, but Karen was unbelievable today, playing very aggressive and serving really good."