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The Spaniards saw off Argentinian pair Maximo Gonzalez and Andres Molteni in straight sets 7-6 (6-4) 6-4 in one hour and 49 minutes on Saturday.

Alcaraz, who began the day with a victory in his singles debut, made a nervy start as he dropped his first serve, but Nadal soon helped to settle the nerves.

They got the vital break in the next game, though there was little to separate the teams after that with a tie-break necessary to put Alcaraz and Nadal in front.

Gonzalez and Molteni rallied in the second set, racing into a 3-0 lead, but could not prevent a fight back as Alcaraz and Nadal won the next three games.

After another vital break for the Spaniards at 4-4, Nadal then served out the match to set up a meeting with either Dutch pair Tallon Griekspoor and Wesley Koolhof or Marton Fucsovics and Fabian Marozsan of Hungary.

Data Debrief: Living up to expectations

It is the match-up that everybody was waiting for at the Olympics, and despite a sluggish start, Alcaraz and Nadal soon turned on the style.

They hit 17 winners, and even though Alcaraz's first service game was not his usual best, they went on to win 46 of their 64 service points (72%).

The Spaniard – who captured his fourth grand slam title at Wimbledon earlier this month – needed just one hour and 12 minutes to overcome Habib, who is ranked 275th in the world by the ATP.

Alcaraz had to save break point in the very first game but immediately set about putting Habib under pressure from there, getting a quickfire break to take control of the opener.

Habib hit just three winners throughout the first set, with 16 unforced errors costing him as Alcaraz served with supreme confidence, only dropping one point in a span of six games on his own serve.

Another break in the first game of the second set had Alcaraz truly in charge, and he gave nothing away from then on as he eased to victory.

He will face Britain's Cameron Norrie or the Netherlands' Tallon Griekspoor in the second round, with the duo yet to face off due to rain suspending play on the outside courts.

Data Debrief: Alcaraz goes from strength to strength

Returning to the scene of last month's French Open triumph, Alcaraz was barely troubled as he improved his record at clay-court events to 12-3 for the year.

He was far too good for Habib on Saturday, slamming 26 winners to his opponents' five and causing problems whenever he was able to get to the net, where he won 13 of 16 points on approach (81%).

He will return to the court to partner Rafael Nadal in the doubles later on Sunday, versus Argentine duo Maximo Gonzalez and Andres Molteni.

The world number one made history on Sunday by beating Matteo Berrettini in the Wimbledon final to match Roger Federer and Rafael Nadal on 20 grand slam titles.

Djokovic has won all three majors in 2021 and recently suggested he would represent Serbia at this year's Olympics, with the tennis tournament due to begin on July 24.

However, with organisers this week confirming spectators will be banned from attending events in Tokyo amid rising coronavirus cases, Djokovic is unsure if he will travel to Japan.

"My plan was always to go to Olympic Games, but right now I'm a little bit divided," he said after his sixth Wimbledon triumph. 

"I also hear that there's going to be a lot of restrictions within the [Athletes'] Village. Possibly you would not be able to see other athletes perform live. 

"I can't even have my stringer that is very important part of my team. I can't have a stringer. I'm limited with the amount of people I can take in my team as well.

"It's kind of 50-50 because of what I heard in the last couple days."

Djokovic has competed at the Games on three previous occasions, but unlike Nadal and Federer he has never previously claimed a gold medal, the bronze he won in 2008 being the best the 34-year-old has managed.

Nadal, Dominic Thiem, Roberto Bautista Agut, Denis Shapovalov, Nick Kyrgios, Simona Halep and Serena Williams have previously confirmed they will not play at the Olympics.

Switzerland's Federer, who won gold in the men's doubles in Beijing 13 years ago, has yet to make a decision on his participation.

Thursday's men's singles draw saw Djokovic paired with Australia's Matthew Ebden in the first round, with Nadal taking on Marton Fucsovics.

The legendary duo – who have won 46 grand slam singles titles between them – will meet in the second round if they both advance through their openers this weekend.

Djokovic and Nadal have previously faced off on 59 occasions, with the Serbian winning 30 of those contests but losing four of the last six, the most recent being a Nadal victory in four sets in the 2022 French Open quarter-finals.

Nadal's participation at the Games was thrown into doubt when his coach Carlos Moya said he had suffered a "setback" on Thursday and required 48 hours of rest.

If Nadal – who is widely expected to retire later this year – does make the tournament, Djokovic is looking forward to the prospect of facing him for a 60th time.

"Obviously he hasn't played much. His ranking dropped, so there was always going to be that possibility of me meeting him in an early round and there we go," Djokovic said.

"It's going to be a spectacle, definitely, if we get to meet. We will spread some fireworks on the court, like the good old times. 

"I hope we get to meet because it will probably be one last dance for the both of us."

Djokovic is set to appear at his fifth Olympics in the French capital, the joint-most by any male player since the sport returned to the Games in 1988 (with Yen Hsun Lu).

He is the player with the most matches played (19) and joint-most matches won (13, level with Roger Federer) at the Olympics since 1988.

However, his best result at the Games remains a Bronze medal at Beijing 2008, when he was beaten by eventual gold medallist Nadal in the semi-finals.

Djokovic lost the bronze medal match to Pablo Carreno Busta at the delayed Tokyo Games three years ago, also losing to Juan Martin del Potro at both London 2012 and Rio 2016.

The Swiss great, a winner of 20 grand slam titles, had hoped to make a farewell Olympic Games appearance last year, only for the pandemic to mean the event was postponed for 12 months.

Both the Japanese government and the International Olympic Committee have not swayed from their stance that the Games will go ahead despite a strong swell of public support for a cancellation.

With Japan struggling to contain the COVID-19 virus, however, and Tokyo still in a formal state of emergency, there remain major doubts over whether it is realistic for thousands of international visitors to come to the country in July and August.

Federer has heard the confident voices, but he also is aware that many residents of Tokyo are against the Games happening this year.

"Honestly I don't know what to think. I'm a bit between the two," Federer told Swiss television station Leman Bleu.

"I would love to play in the Olympics, win a medal for Switzerland. It would make me especially proud. But if it doesn't happen because of the situation, I would be the first to understand.

"I think what the athletes need is a decision: is it going to happen or is it not going to happen?

"At the moment, we have the impression that it will happen. We know it's a fluid situation. And you can also decide as an athlete if you want to go. If you feel there's a lot of resistance, maybe it's better not to go. I don't know."

Federer, who is returning from a long knee injury lay-off, has played at four previous Olympics, winning doubles gold with Stan Wawrinka in Beijing in 2008 and silver in singles at London 2012, where Andy Murray denied him in the final at Wimbledon.

He is set to play his second comeback tournament next week at the Geneva Open, building up to a French Open appearance, with Wimbledon on the horizon.

He and wife Mirka and their family are likely to be spending several weeks apart as Federer co-operates, where required, with tournament bubbles, limiting the size of player entourages.

"It's going to test a little the situation at home," Federer said. "I've spoken about it a lot with Mirka. Now it's the comeback which is the priority."

An Olympic gold medal is the one major honour to have eluded Federer during his decorated singles career.

The 20-time grand slam champion won gold in doubles alongside Stan Wawrinka in 2008 but was beaten by Andy Murray in the singles final in 2012 and pulled out of the tournament in 2016 to recover from a knee injury.

Rafael Nadal will not feature in Tokyo, having decided to skip Wimbledon and the Olympics to help him recuperate after the clay-court season.

Federer has grown significantly more selective over his schedule in the latter stages of his career as he has sought to look after his body.

Asked about his participation at the delayed Games, which begin next month, Federer told a media conference: "It's still my intention to go to the Olympic Games.

"But we will reassess everything after Wimbledon. It is my goal to play as much tournaments as possible. But it really depends on results and how the body is feeling.

"I wish I could tell you more. At the moment things are not as simple as in the past. With age, we have to be more selective, I can't play it all."

Federer starts his campaign for a ninth Wimbledon title when he faces Adrian Mannarino on Tuesday.

The Swiss has won all six of his meetings with Mannarino, including matches at Wimbledon in 2011 and 2018.

Olympic gold in singles is one of the few honours missing from Federer's glittering resume, the 20-time grand slam champion having won silver in 2012, losing the gold medal match to Andy Murray less than a month after beating the Briton in the Wimbledon final.

While Murray will be in Tokyo to attempt to defend his title again having successfully retained it in 2016, Federer – a doubles gold medallist in 2008 – has elected not to make the trip to Japan.

"During the grass-court season, I unfortunately suffered a setback with my knee, and have accepted that I must withdraw from the Tokyo Olympic Games," Federer wrote in a statement on Twitter.

"I am greatly disappointed, as it has been an honour and highlight of my career each time I have represented Switzerland.

"I have already begun rehabilitation in the hopes of returning to the tour later this summer. I wish the entire Swiss team best of luck and I will be rooting hard from afar. As always, Hopp Schwiz!"

Federer missed most of the 2020 season due to persistent right knee problems that led him to undergo two surgeries.

The length of his recovery forced Federer to miss this year's Australian Open but he made his return to the tour in time for the French Open, reaching the fourth round before withdrawing to focus on the grass-court season.

Yet he was stunned by Felix Auger-Aliassime in the second round in Halle and was often unconvincing in progressing to the quarter-finals at Wimbledon, where his quest for a ninth title was ended by Hubert Hurkacz, the Pole becoming the first player to win a set 6-0 against Federer at the All England Club.

The 39-year-old's withdrawal makes him the latest tennis big name to pull out of the Tokyo Games. On the men's side, Rafael Nadal and Dominic Thiem decided against competing, while Serena Williams confirmed before her first-round retirement at Wimbledon that she had no plans to play at the Olympics.

World number one Novak Djokovic has said he is "50-50" on going for his first Olympic title. Having won all three majors so far this year, Djokovic is in prime position to become the first man to do the 'Golden Slam' in the same season. Steffi Graf achieved the feat in 1988, with a sweep of the majors followed by her victory at the Seoul Olympics.

Nadal is widely expected to retire from tennis later this year, with the Olympics set to represent his swansong at Roland-Garros, where he has won 14 French Open titles.

He will play in both the singles and doubles tournaments, partnering current French Open and Wimbledon champion Carlos Alcaraz for the latter competition.

Nadal and Alcaraz will face Argentina's fourth-seeded pair Maximo Gonzalez and Andres Molteni in a difficult first-round matchup in the doubles tournament.

Nadal is one of just two players to have won Olympic gold in both singles and doubles since the sport returned to the Games in 1988, doing so at Beijing 2008 (singles) and Rio 2016 (doubles) – Nicolas Massu triumphed over both events at Athens 2004.

In the singles, Nadal will take on Hungary's Marton Fucsovics in the opening round, and the prize could be a second-round date with Djokovic, who faces Australian Matthew Ebden first.

They are on the same side of the draw as third seed Alexander Zverev, who faces Jaume Munar first, and seventh seed Taylor Fritz, who opens against Alexander Bublik.

On the opposite side of the bracket, Alcaraz will start his campaign against Hady Habib, with Britain's Cameron Norrie a potential second-round opponent.

Fourth seed Daniil Medvedev faces Rinky Hijikata in his first match, while fifth seed Alex de Minaur is a potential quarter-final opponent for Alcaraz.

Britain's Andy Murray withdrew from the singles event to concentrate on his doubles bid alongside Dan Evans on Thursday, and the duo will face Kei Nishikori and Taro Daniel of Japan first.

Should they advance, home favourites Arthur Fils and Ugo Humbert could await in round two, with Taylor Fritz and Tommy Paul potential quarter-final foes, though the Americans will have to overcome Canada's Milos Raonic and Felix Auger Aliassime to get that far.

Murray and Evans cannot face Nadal and Alcaraz until the final. 

Iga Swiatek is the strong favourite in the women's draw, having won four French Open titles on the Paris clay. Romania's Irina-Camelia Begu is her round-one opponent.

On her same side of the draw, there is a huge round-one clash between Naomi Osaka and 2016 silver medallist Angelique Kerber, who announced on Thursday that she will retire after the Games.

Elena Rybakina and Danielle Collins are also on that side of the draw, while Coco Gauff starts against Ajla Tomljanovic on the opposite side of the bracket.

The 22-time major champion is widely expected to retire at the end of this year, though is preparing for a final swansong at Roland-Garros, where he has won 14 titles.

Nadal is set to play in the singles and doubles tournaments of the Olympics, partnering current French Open and Wimbledon champion Carlos Alcaraz for the latter competition.

Yet his participation has become doubtful after coach Carlos Moya confirmed Nadal had cancelled his training session on Thursday due to a hamstring issue.

"It was a setback and we decided that today Rafa would rest and not train to recover," Moya said, as quoted by Spanish journalist Rafael Plaza.

"We are going to give ourselves 48 hours, we have to wait."

The 38-year-old is reportedly feeling soreness in both his left and right hamstring having pulled out of a scheduled practice session with Alexander Zverev.

Alcaraz had been partnering Nadal throughout the week during training on the clay courts of Paris, though the veteran's feature has now been thrown under a cloud of doubt.

Nadal is one of just two players to have won Olympic gold in both singles and doubles since the sport returned to the Games in 1988, doing so at Beijing 2008 (singles) and Rio 2016 (doubles).

In the singles in the French capital, Nadal has been drawn against Hungary's Marton Fucsovics in the opening round, and the prize could be a second-round date with long-term rival Novak Djokovic.

After being postponed last year due to the coronavirus pandemic, the Games are scheduled to start in Tokyo on July 23.

Naomi Osaka said she would be willing to quarantine ahead of the Olympics, with players having gone through similar in preparation for the Australian Open.

Nadal, an Olympic gold medallist in singles and doubles in 2008 and 2016 respectively, said he would listen to the experts, but acknowledged quarantining could be tough.

"It's the same as always. I am nobody to have a clear opinion on that.  I am just a tennis player, a human person that doesn't have enough knowledge about all the situation," the Spanish star told a news conference on Sunday.

"What we have to do is just follow the instructions of what the people who really have the right knowledge of all this stuff give to us. What's going to happen in Tokyo for the Olympics, if the Olympics are going to happen or not, or if we have to do quarantine before Olympics for 15 days or not, seems like a sports perspective very difficult because it's difficult for us, I don't know, combining our Tour with another 15 days of quarantine to play Olympics. It looks difficult to fix it in our calendar.

"But, as I said, we're going to do what the people who know about virus and who know about protecting the people in every single country, [we] are going to just follow their instructions."

Asked if his intention was to go, Nadal said: "I think everybody wants to play in Olympic Games, then let's see what's going on."

Nadal and Spain will begin their ATP Cup campaign against Australia on Tuesday.

The 20-time grand slam champion was knocked out of the French Open at the semi-final stage by eventual winner Novak Djokovic.

And, with just a two-week gap to the grass-court slam in London, the 35-year-old has opted against taking part at the All England Club or the Games in Tokyo.

"Hi all, I have decided not to participate at this year's Championships at Wimbledon and the Olympic Games in Tokyo," the Spaniard tweeted.

"It's never an easy decision to take but after listening to my body and discuss it with my team I understand that it is the right decision.

"The goal is to prolong my career and continue to do what makes me happy, that is to compete at the highest level and keep fighting for those professional and personal goals at he maximum level of competition."

Nadal explained that the quick turnaround from a gruelling campaign in Paris to another tough schedule at Wimbledon presented too much of a risk to his fitness.

"The fact that there has only been two weeks between RG [Roland Garros] and Wimbledon didn't make it easier on my body to recuperate after the always demanding clay court season," he said.

"They have been two months of great effort and the decision I take is focused looking at the mid and long term.

"Sport prevention of any kind of excess in my body is a very important factor at this stage of my career in order to try to keep fighting for the highest level of competition and titles.

"I want to send a special message to my fans around the world, to those in the United Kingdom and Japan in particular.

"The Olympic Games always meant a lot and they were always a priority as a Sports person, I found the spirit that every sports person in the world wants to live. I personally had the chance to live 3 of them and had the honor to be the flag bearer for my country."

Nadal is a two-time Wimbledon champion and took gold at the 2008 Olympics in Beijing.

The 24-time grand slam champion will target a gold medal for the first time, with his appearance in Paris set to be his fifth at the Olympics.

Djokovic won a 2008 bronze medal in Beijing after losing to eventual winner Rafael Nadal in the semi-finals before beating James Blake for third place.

He came fourth at London 2012 after suffering defeats to Andy Murray and Juan Martin del Porto in the final stages and lost early at Rio 2016 before narrowly missing out on a medal in Tokyo three years ago, with Alexander Zverev and Pablo Carreno Busta getting the better of him to end a historic bid for a Golden Slam.

Djokovic, 37, said in April that winning an elusive gold medal was a priority for him this year, but there was some uncertainty over his participation after he withdrew from the French Open before his quarter-final match this month through injury.

The Serbian suffered a torn meniscus in his right knee and underwent surgery but now looks to be on track to return to Roland-Garros for the Games, with Dusan Lajovic also selected for Serbia.

"Team Serbia for Paris 2024 got new representatives," the Serbian Olympic Committee announced. 

"Tennis players Novak Djokovic and Dusan Lajovic fulfilled the requirements, according to the ATP ranking, and confirmed their performance at the Olympic Games."

Djokovic's involvement in the men's tournament comes as a boost for the Paris Games after some high-profile female players like Aryna Sabalenka, Ons Jabeur and Emma Raducanu announced they would not be participating.

The Olympic tennis tournaments are scheduled to run from July 27 until August 4.

It is not yet known whether Djokovic will be able to participate at Wimbledon, which takes place before the Olympics.

Wimbledon begins on July 1 and Djokovic is a seven-time champion at the event, just one title behind the men's singles record held by Roger Federer. 

Djokovic lost an epic final to Carlos Alcaraz at last year's Wimbledon.

Two-time Olympic gold medallist Andy Murray was also offered a spot and will compete in what could be the final tournament of his career.

Two spots are reserved for former Grand Slam winners, but Raducanu, the 2021 US Open champion, has decided against going to Paris as she continues her comeback from injury.

Raducanu is ranked too low to automatically qualify after wrist and ankle surgery last year forced her away from the sport.

She also missed the French Open, played on the same courts that will stage the Olympics, earlier this year to ensure she would be fit for the grass-court swing of the season.

Iain Bates, head of GB's Olympic tennis team, said: "I have had various conversations with Emma over the last couple of weeks and a slightly longer period where it's very clear how much being part of a British team at an Olympics would mean to her.

"I think she feels this isn't going to be the right timing for her for this summer.

"She's hopefully got many Olympics ahead of her. I'm very comfortable with the decision that she's made."

Meanwhile, Murray, who won gold in London 2012 and Rio 2016, will compete in his fifth Olympic Games and has been named alongside debutants Jack Draper, Cam Norrie and Dan Evans.

Katie Boulter is also set to make her Olympic debut as the only British woman to qualify by ranking for the Games.

The ITF will announce the full entry list for Paris 2024 on July 4.

Rivals Rafael Nadal and Roger Federer, citing respective scheduling and injury issues, have each withdrawn from Tokyo 2020.

But Djokovic confirmed on Thursday he will travel to Japan in pursuit of a groundbreaking achievement.

Only women's tour legend Steffi Graf has previously won all four majors and the Olympics in the same year, doing so in 1988.

Doubles superstars Bob and Mike Bryan held all five titles at once but collected them across 2012 and 2013, while Andre Agassi and Nadal are the only two men's singles players to achieve the feat across an entire career.

Djokovic has already triumphed at the Australian Open, French Open and Wimbledon in 2021, leaving Tokyo and the US Open still to conquer.

The 20-time grand slam champion – a record he tied at the All England Club on Sunday – has entered the Games three times previously but earned only a single bronze medal. Andy Murray is the two-time defending champion.

At Flushing Meadows, Djokovic is a three-time winner.

The 34-year-old confirmed his Olympics plans in a social media post as he sent a message to a young Japanese fan celebrating his sixth birthday.

"Cannot disappoint my little friend Koujirou," Djokovic wrote. "I booked my flight for Tokyo and will proudly be joining #TeamSerbia for the Olympics."

He had said following his Wimbledon win last week: "My plan was always to go to Olympic Games, but right now I'm a little bit divided."

Djokovic added limitations on his travelling party and potentially being unable to watch fellow athletes had reduced the likelihood of an appearance to "50-50".

But he will now feature, even if former Wimbledon champion Pat Cash believes the calendar Grand Slam – winning the four majors but not the Olympics – has to be the Serbian's priority.

Cash told Stats Perform: "It's the Olympics, okay – maybe he wants to do that, but certainly his goal is now to try and win all four grand slams in the calendar year.

"He has done four in a row, but he hasn't done them in the same year, which is very, very tough to do.

"There is a reason why I think one person has done it in [men's] professional tennis – Rod Laver and it was in 1969, so it's not easy to do.

"But I really do think it's in his sights and that has got to be his priority.

"It's absolutely the absolute peak of our sport to win all four grand slams in one year."

The world number one lost 6-4 6-7 (6-8) 6-3 to Pablo Carreno Busta in the singles bronze medal match, smashing one racket against a net post and tossing another into the stands in gestures of frustration.

Djokovic then cited a shoulder injury as he pulled out of the mixed doubles third-place match. That decision meant Ash Barty and John Peers of Australia took bronze, with Djokovic and his unfortunate Serbia partner Nina Stojanovic finishing fourth.

"I am dealing with injuries. Not one, more than one," Djokovic said in an interview with Serbian media, according to tennismajors.com. "I hope that it won't stop me from going to the US Open, which is my next big goal.

"I feel bad for Nina because we did not fight for a medal in mixed, but my body said 'enough'. I have played under medications and abnormal pain and exhaustion."

The 34-year-old Djokovic said he had put his "very last source of energy" into the tournament and was satisfied with his effort, with a semi-final defeat to Alexander Zverev on Friday having left him resigned to a battle for what by his standards was perceived as a consolation prize.

But Djokovic added: "I know I've not played well today, and yesterday in the second and third set.

"The exhaustion, both physical and mental, got to me and it's unfortunate that in the most important matches I just didn't deliver, but I gave it all."

Djokovic suggested the Paris Olympics in 2024 were a possible target, although he must be becoming sick of Olympic tennis by now, having only one bronze to show for four attempts to win gold.

He took bronze in 2008 but lost to Argentina's Juan Martin del Potro both in the third-place match at London 2012 and the first round at Rio 2016.

Now there is more Games agony to digest, as well as a need to reboot ahead of the upcoming North American hardcourt swing and that US Open campaign. His hopes of a calendar Golden Slam are over but a sweep of the grand slams remains a possibility, having already landed the Australian Open, French Open and Wimbledon titles.

"I've had some heart-breaking losses at the Olympics Games," Djokovic said. "I know that those losses have usually made me stronger. I know that I will bounce back. I will try to keep going for the Paris Olympic Games. I will fight for my country to win medals."

Carreno Busta's reaction was thoroughly refreshing, with the Spaniard jubilant to secure a medal.

He said: "This week has been a very harsh week mentally for me. When I saw Novak lost, and I had to play him for this medal, I had my doubts.

"But last night I slept like I haven't slept in Tokyo. I slept for nine hours straight, that was an advantage to me. I came on to the court today knowing Spain was behind me.

"This is even more incredible than winning other tournaments. I've won Davis Cup, I've gone far in other tournaments, but winning an Olympic medal is indescribable. Words fail me, I felt Spain rallying behind me. A bronze medal is a dream come true for me."

The knock-on effort of Djokovic's withdrawal from the mixed doubles meant Barty and Peers added to Australia's medals haul without having to step on court for the third-place play-off.

Barty insisted she and Peers were worthy bronze medallists, saying: "It's incredible. It's unique circumstances and heartbreaking for Team Serbia not to get out on court.

"But for Johnny and I this is a dream come true for us. I feel like we've really deserved this one."

Spain's Pablo Carreno Busta beat the world number one 6-4 6-7 (6-8) 6-3 to finish third in men's singles.

The shock result followed a day on from Djokovic's hopes of a Golden Slam being crushed by defeat to Alexander Zverev in the semi-finals.

In the wake of his singles third-place match setback, Djokovic also pulled out of the mixed doubles bronze match, citing a left shoulder injury.

Having already clinched the Australian Open, French Open and Wimbledon titles, Djokovic was eyeing gold at the Games before heading to the US Open in August, aiming to land the five biggest prizes in tennis in the same season.

That has never been achieved in a calendar year by a man, and Djokovic could not even manage a consolation prize from his singles mission in Japan. How serious his injury is now remains to be seen.

After levelling the singles match by taking the second-set tie-break, Djokovic boiled over in the first game of the decider, firstly when flinging his racket several rows back from the middle of the court after Carreno Busta put away a volley at the net.

Djokovic picked another racket from his bag but petulantly demolished that against a net post after dropping the third game to slide 3-0 behind, receiving a warning from the umpire for that violent outburst.

His anger may have been explained by injury or by his disappointment on Friday, when, as well as losing to Zverev, Djokovic and Serbian team-mate Nina Stojanovic were beaten in the semi-finals of the mixed doubles.

Djokovic would have had one final shot at a medal from his Tokyo trip to come later on Saturday, with the 34-year-old and Stojanovic due to face Ash Barty and John Peers in another match for bronze.

However, shortly after his singles exit, it was announced that Djokovic had pulled out of that match, handing Barty and Peers the medal.

Amid the anger and frustration exhibited on court by Djokovic, it was a banner day for Carreno Busta, as Spain celebrated another tennis medal, having won at least one in eight of the last nine Olympics.

The 30-year-old fell to the court in joy at the end of the two hours and 47 minutes it took him to defeat the world number one, his elation a sharp contrast to the emotions of his beaten opponent.

The Serbian, who has won the Australian Open, French Open and Wimbledon already in 2021, is chasing the gold medal that would leave him one step away from the first tennis calendar 'Golden Slam' by a man.

Should he triumph in Japan over the next fortnight, Djokovic will head to the US Open in late August needing to win in New York to complete the full set.

Steffi Graf, who in 1988 won all the slams and gold at the Seoul Olympics, is the only player in tennis history to have completed such a sensational season.

Djokovic said such a feat was becoming a "more and more realistic" target, as he spoke in a Serbia team news conference, but the last time he stepped off the singles court at an Olympic Games, he was in tears, having lost in the first round at Rio to Juan Martin del Potro.

There is no danger of Djokovic running into his Olympic nemesis in Tokyo, with Del Potro, who also beat Djokovic in a bronze-medal match at the London 2012 Olympics, not a part of Argentina's squad as he battles back from four knee operations.

Looking at his own prospects for Tokyo and the rest of the year, Djokovic said: "It is still a long way to go... I put myself in a very good position. But I will take things very slowly and cautiously.

"It's an approach I need to have because in the past I wasn't probably fully experienced in that approach. And I started to feel there were a lot of distractions around that influenced my performance.

"I know there are a lot of things on the line, a lot of history on the line. I'm privileged to be in this position. I worked very hard to be here, with my team, of course. But let's talk about history if everything goes great."

After his singles loss in Rio, Djokovic and Nenad Zimonjic lost in the second round of doubles to Brazilians Bruno Soares and Marcelo Melo.

A bronze from Beijing 2008 is all Djokovic has to show for his Olympics career to date, but he is a hot favourite for the title in Tokyo, where he will start against Bolivia's world number 139 Hugo Dellien.

The 34-year-old Djokovic said he "would be delighted to ask" Graf how she achieved her 1988 clean sweep.

"When I was thinking about her ultimate achievement... I did not think it... I don't want to say 'achievable', but [I thought] there was a slim chance that someone could make it again, both male and female," Djokovic said.

"But right now it seems more and more realistic. Of course, it is one of my goals and dreams."

Djokovic has neither Roger Federer nor Rafael Nadal as rivals in Tokyo, with Federer missing after reporting a knee injury setback and Nadal electing to give the event a miss.

The 'Big Three' each have 20 grand slam titles now, following Djokovic's hot streak, and the Serbian admits it is unusual for both superstars to be absent.

"I have not experienced too many big tournaments in the past 15 years without Roger and Rafa playing. So it's a little bit strange," Djokovic said. "I'm used to seeing at least one of them. But still, some of the best players in the world are here.

"The guys who are in the top six, seven in the world, they are the biggest competitors or candidates for winning a medal. But potentially I am meeting with them in the later rounds."

After winning Wimbledon for a sixth time, Djokovic surprised many by claiming he could skip the Olympics, but he was reeled in by the appeal of representing his country, perhaps for the final time in the Games.

"Without the key element of any sports events – the crowds, the fans, that energy – it's different, but it is still the Olympic Games," he said.

"I was in a dilemma for a little bit, but I decided to come, and I'm glad because there are many more things that are beautiful about the Olympic Games. So I will try to focus on those things."

Osaka was given the honour of carrying the torch on the short final leg at the Japan National Stadium before walking the steps to light the flame and end the opening ceremony.

The four-time grand slam champion is the face of the Tokyo Games in her home country, creating extra pressure on her shoulders as she bids to strike gold.

Djokovic appreciates the absences of legendary names Roger Federer and Rafael Nadal is a blow, but he believes Osaka's presence is crucial for tennis in the battle for media coverage at the Games.

"It cannot be better for our sport, you are representing yourself, your country but also your sport in the Olympic Games, you're trying to get the hype and the attention towards our sport as much as you possibly can, so we're all contributing to that in the Olympic Village," Djokovic said when asked about Osaka's role in Friday's ceremony.

"There's a lot of attention towards the tennis players which is great, from the other athletes which is very nice to see, very nice to experience.

"Obviously you don't have Roger or Rafa. They are big stars and legends of our sport, but still there's quite a lot of great athletes, top players. Naomi is a home favourite and a lot of eyes are on her.

"Being at home playing is a lot of pressure, but it's great for our sport just in general to see that there's a lot of attention towards it."

Djokovic was speaking after overcoming Hugo Dellien with ease in his opening outing in the men's singles tournament, the Serbian triumphing 6-2 6-2 in just over an hour.

The quick win allowed the recently crowned Wimbledon champion to avoid staying out for too long in the Tokyo heat, an issue that led to Daniil Medvedev calling for matches to be pushed back to later in the day, allowing players to compete during the evenings when the temperatures have dropped.

"I agree with him 100 per cent," Djokovic said of Medvedev's suggestion. "I actually asked as well.

"My team captain, Viktor Troicki, was speaking to the referee a couple of times. To be honest, I don't understand why they don't start matches at say 3pm.

"I've heard for tennis there is some kind of curfew they have to finish at midnight, but if that's the case, I've just finished the last match and it's not even 5pm, we still have seven hours to play. 

"They have lights on all the courts, they're going to make life much easier for all of us tennis players, I just don't understand why they don't move it. 

"It's actually for the television broadcasters even better, because the later you play, the better it is for the United States and the time zones in Europe.

"I don't know, maybe the ITF (International Tennis Federation) can give you a better answer to why they chose to be played in the middle of the day. I doubt they will change the decision, but we're hoping that they will."

The world number one is yet to drop a set at the Tokyo Games after running out a 6-2 6-0 winner against home favourite Nishikori, who claimed bronze in Rio five years ago.

Having already won the Australian Open, French Open and Wimbledon this year, Djokovic is aiming to become the first male player of the Open era to complete the Golden Grand Slam.

Should he claim gold in Tokyo and go on to triumph at the US Open, he would become only the second player overall to achieve the feat, after Steffi Graf in 1988.

However, the Serbian has never reached an Olympic final – his best result coming in for the form of a bronze medal in Beijing.

"Matches are not getting easier, but my level of tennis is getting better and better," Djokovic told reporters after setting up a last-four tie with Alexander Zverev.

"I've done that many, many times in my career. I know that I'm the kind of player that the further the tournament goes, the better I'm feeling on the court.

"That's the case here, [it was] my best performance of the tournament tonight against a very good opponent."

DANIIL DUMPED OUT

Standing in the way of Djokovic and a shot at the gold medal is fourth seed Zverev.

The big-serving German saw off Jeremy Chardy 6-4 6-1 and like Djokovic is yet to drop a set at the tournament.

World number five Zverev, who hit 11 aces during the contest, broke early on the way to edging a closely fought opening set. The US Open finalist then went into overdrive with three breaks on the way to sealing the deal.

There was, however, no joy for second seed Daniil Medvedev, as he went down 2-6 6-7 (5-7) against Spain's Pablo Carreno Busta, who is looking to replicated Rafael Nadal's effort from 2008.

"Today, he could win a Masters easily, and yet he's never been in any final of those," the Russian said of his opponent.

"With the level he showed here today, he can get to the final of a Grand Slam easily. I couldn't play better than what I did today. It was not easy to play and I'm really disappointed with myself and for my country to lose in the quarters."

FROM RUSSIA WITH LOVE

Despite Medvedev's exit, Russia – or, at least, the Russian Olympic Committee – will be represented in the semi-finals by Karen Khachanov.

A quarter-finalist at Wimbledon earlier this month, the 12th seed built on his momentum by overcoming Ugo Humbert in three sets.

Khachanov took the opener on a tie-break but was pegged back by the Frenchman in the second as the contest went to a decider.

But he established early control by breaking to love in game four before holding out to prevail 7-6 (7-4) 4-6 6-3.

From a set and a break up, Djokovic dropped a staggering eight games in a row on his way to a 1-6 6-3 6-1 loss.

The 34-year-old Serbian had been unsure about coming to the Games but was swayed by the pride he takes in representing his country and the tantalising opportunity to add a gold medal to a potential clean sweep of the grand slams.

He has already won the Australian Open, French Open and Wimbledon, and will head to the US Open in August as a heavy favourite regardless of this setback.

But this was just not Djokovic's day, despite him making a whirlwind start and dominating until the point he broke to lead 3-2 in the second set. From there, Zverev seized control. 

When Djokovic volleyed into the net to make it 3-3, dropping serve for the first time in the match, it looked like just a minor stumble.

Yet suddenly he was struggling for form and did not win another game until he was already 4-0 behind in the deciding set.

Zverev was playing blindingly brilliant tennis and was proving obdurate too, saving four break points in the second game of the third set.

He clinched victory with a blazing backhand winner, and goes on to face Russian Karen Khachanov in the final.

The result means Djokovic, like Roger Federer, seems fated never to win the Olympic singles gold medal. And it leaves Steffi Graf as the only player to ever win a calendar Golden Slam, having done so in 1988 when she added the Seoul Olympics title to her haul of majors.

Russian Olympic Committee's Khachanov fended off Spain's Pablo Carreno Busta with some ease in the first semi-final, with the world number 25 sweeping to a 6-3 6-3 victory in an hour and 19 minutes.

He won 26 of 28 points on first serve to freeze out Carreno Busta, who had only one break point all match and could not take that opportunity.

"It's just a pure happiness, a pleasure to be here to live those moments, these kind of memories will stay forever," Khachanov said.

Khachanov delivered a rock solid display, with his serve and forehand at their best, barely giving his opponent a sniff of an opportunity as the Moscow-born 25-year-old established a firm grip.

"That's the way I prepared, against every opponent you play a little bit differently," Khachanov said. "The final will be another story, another match, another day. I hope it will be the same."

Carreno Busta, who will face Djokovic for the bronze medal, said: "It was not the best match I have played, but Karen was unbelievable today, playing very aggressive and serving really good."