Chelsea top Women's Champions League group as James double downs PSG
Emma Hayes' team knew a draw would suffice as they targeted first place on Thursday, but they ultimately enjoyed a routine outing as James added to Sam Kerr's first-half stunner.
Kerr fired into the top-right corner from 20 yards out to hand Chelsea the lead, before James added two well-taken finishes as the Blues finished their group-stage campaign with an unbeaten record.
In the group's other game, Real Madrid bowed out on a positive note as Teresa Abelleira scored twice in a 5-1 rout of Vllaznia, with Scotland international Caroline Weir also on the scoresheet.
In Group B, meanwhile, two-time champions Wolfsburg clinched top spot by thrashing Austrian side St Polten 8-2 away from home, with eight different players netting for the visitors.
Roma will join Wolfsburg in the quarter-finals after wrapping up their campaign with a 3-0 victory at Slavia Praha, with Valentina Giacinti, Beata Kollmats and Elena Linari scoring as the Italians finished one point behind the German giants.