Volcanoes made 260-8 off their 50 overs as left-hander Keron Cottoy top-scored with a 64 off 47 balls with four fours and five sixes.
In reply, Jamaica had a bad start were 61-5 in the 15th over before being bowled out for 168 in the 37th over. Left-arm spinner Larry Edward celebrated his 26th birthday in style with a match-winning spell of 3-36 off 10 overs.
When Windwards batted, Andre Fletcher made 60 from 51 balls at the top of the order with four fours and three sixes.
Cottoy was named the CG Insurance Man-of-the-Match, as he continued his good form to follow up his career-best 72 in the previous match against Trinidad & Tobago Red Force. Volcanoes were 171-5 after 40 overs but Cottoy raised the tempo with a number of breathtaking shots as and the last 10 overs yielded 89 runs.
Andre McCarthy top-scored for Jamaica with a run-a-ball 55 which included six fours and a six as he maintained good form - his previous knocks were 48 against Guyana Jaguars and 40 against Trinidad & Tobago Red Force.
Fabian Allen played a number of brave shots in 39 from 43 balls. At the end, Fletcher showed his new skill set as a leg-spinner and captured the last two wickets.
“It’s always good to perform for your team especially in victories. I’m just glad I’ve been able to put up my hand and bat deep into the innings and it paid dividends,” said Cottoy. “We have to take it one game at a time although it feels good to win two out of three.”
Today: Leeward Islands Hurricanes vs Trinidad & Tobago Red Force at Coolidge Cricket Ground. First ball is 1:30pm (12:30pm Jamaica Time)
The Volcanoes resumed on 101-3 with captain Kavem Hodge (30) and Ackeem Auguste (0) at the crease needing to score 209 to overhaul their first innings deficit of 209 runs.
The pair added a further 26 before Auguste became Merchant’s first scalp of the day for 11.
First innings half-centurion Keron Cottoy joined his captain and the pair put on 36 before Merchant dismissed Cottoy for 21 to leave the Volcanoes struggling at 163-5.
The popular cricket phrase “one brings two” was in full effect as just two balls later, Merchant removed wicketkeeper/batsman Denis Smith for a duck to leave the Volcanoes 163-6.
In the midst of the carnage, Hodge brought up a well-played half century before being the seventh wicket to fall, dismissed by Green for 63 as the Volcanoes slumped to 173-7.
Sherman Lewis (6), Preston McSween (4) and Josh Thomas (0) were the final three wickets to fall as Merchant and Green mopped up the tail to secure the massive win for the Scorpions.
Merchant, who scored 58 when the Scorpions batted, followed up with 5-72 from 28 overs to cap a fine all-round performance while Green ended with 5-46 from 18.2 overs.
Final scores: Windward Islands Volcanoes 137 and 195, Jamaica Scorpions 346.
The Jaguars, thanks to 189 from skipper Leon Johnson, and 107 from Christopher Barnwell had made light work of the Volcanoes’ 318 all-out in the first innings, scoring 426.
That 318 was made on the back of half-centuries from Kaveem Hodge, 53, Keron Cottoy, 56, and Shane Shillingford, 53.
Devendra Bishoo, 4-73, and Veerasammy Permaul, 4-59, were the best of the Jaguars bowling before their batsmen found it easy going to score 426.
Batting a second time, the Volcanoes made it to 46-1 at the close of play on the third day.
Devon Smith, 16, and Hodge, 17, are the not-out batsmen with Cato the only man back in the pavilion, falling leg-before off the bowling of Raymon Reifer.