Berlin Open top seeds Ons Jabeur and Maria Sakkari progressed with relative ease from their first-round matches, but Aryna Sabalenka and Garbine Muguruza were not so fortunate.
World number four Jabeur, who will team up with Serena Williams at the Eastbourne International, suffered a shock first-round exit at the French Open, but the Tunisian showed no signs of that defeat having affected her in her first grass-court appearance of the season.
Top seed Jabeur required just 73 minutes to overcome Karolina Muchova 6-3 6-3 on Tuesday, with American qualifier Alycia Parks next up after she defeated Qinwen Zheng in straight sets.
Second seed Sakkari, meanwhile, had a similarly comfortable start to her campaign, beating Leolia Jeanjean 6-3 6-2.
Meanwhile, reigning champion Liudmila Samsonova took her place in round two with a 7-5 6-1 victory over Tamara Zidansek.
Samsonova beat Belinda Bencic to claim the title in 2021, and the pair will meet again the quarter-finals should they win respective second-round ties against Veronika Kudermetova and Anna Kalinskaya.
But Kudermetova goes into her clash with Samsonova on a high, having eliminated third seed Sabalenka in a 2-6 7-5 6-4 comeback victory.
WTA Finals champion Muguruza will not be in round two after the Spaniard fell foul of Germany's Andrea Petkovic, who prevailed 7-6 (10-8) 6-4.
"I really do believe that in these really close matches, the simple and little shift of energy can make the difference," Petkovic said.
"If you have the crowd on your side, and they are willing you to the win somehow, I think that can really make a difference."
At the Birmingham Classic, top seed Jelena Ostapenko booked a second-round meeting with Dayana Yastremska.
While Yastremska beat Magda Linette in straight sets, Ostapenko was made to work, with the Latvian requiring two hours to overcome Canada's Rebecca Marino 6-2 5-7 6-3.
Fourth seed Elise Mertens was ditched out by Caty McNally, while former world number two and two-time major champion Petra Kvitova lost to Beatriz Haddad Maia.
Camila Giorgi, the third seed, leads Tereza Martincova after claiming a close first set 9-7 in the tie-break before the match was suspended.
Alcaraz begins Madrid Open campaign with emphatic win
Carlos Alcaraz continued his fine record at the Madrid Open with an emphatic 6-2 6-1 victory over Alexander Shevchenko on Friday.
The two-time defending champion made it 12 straight wins at his home tournament to ensure he will face Brazilian Thiago Seyboth Wild in the last 32.
Alcaraz was playing his first match on the ATP Tour since March 28 after being unable to compete in the Monte-Carlo Masters and Barcelona Open due to an arm injury.
But he was still able to make a fine start to his clay-court season, breaking serve in the first game and racing to victory in only one hour and eight minutes.
Data Debrief
Sometimes the scoreline can be harsh on a beaten player, but on this occasion Alcaraz was clearly dominant, breaking the Kazakh seven times in the match and forcing 11 break-point opportunities while conceding only three for his opponent.
That allowed the Spaniard to claim a dominant victory despite being broken once in each set. He will now turn his attention to a clash with Seyboth Wild, who battled past Lorenzo Musetti with a 6-4 6-4 win.
Reigning champion Sabalenka pushed by Linette at Madrid Open
Aryna Sabalenka got her Madrid Open campaign started with a 6-4 3-6 6-3 win over Magda Linette on Friday.
Sabalenka could not quite hit her peak form against Linette, but the world number two nevertheless got the job done after going the distance.
The Belarusian is hunting a record-equalling third title in Madrid, where she is the reigning champion, though she has not won back-to-back matches at a tournament since winning the Australian Open.
"It's not about being confident," Sabalenka said. "It's about how much you're ready to do to get it. It's about the hard work and to be ready, be ready for the big fights. I feel like confidence is not going to help you in those big matches. It's about staying there and fighting for it."
Data Debrief
Sabalenka (70 per cent, 56-24) is now one of five active players since 2020 to hold a winning percentage of 70 per cent or higher at WTA-1000 events.
Iga Swiatek, Simona Halep, Elena Rybakina and Jessica Pegula are the other players to feature on that list.
Rybakina continues clay winning streak with victory over Bronzetti
In-form Elena Rybakina has moved into the last 32 of the Madrid Open after a straight sets victory over Italian Lucia Bronzetti.
Number four seed Rybakina triumphed 6-4 6-3 on Friday and will next face either Marta Kostyuk or Mayar Sherif.
Rybakina was broken early in each set but ultimately had few problems getting over the line, converting four of her five break points to continue an impressive run of results after winning the Stuttgart Open last week.
She has now won five consecutive WTA matches and has 13 straight wins on clay courts to her name in a superb streak that started one year ago.
Data Debrief: Rybakina in elite company
Since the start of 2020, only two other players have claimed as many 13 consecutive WTA wins on clay, and they are Iga Swiatek and Simona Halep, so Rybakina is in elite company.
Rybakina's last defeat on this surface came in the 2023 edition of the Madrid Open, when she fell to Anna Kalinskaya in her first match, so this win represented a better start to her campaign in the Spanish capital.
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