Reigning Masters champion Dustin Johnson has been grouped with two-time runner-up Lee Westwood to begin his title defence on Thursday.
Johnson returns to Augusta just five months on from a dominant triumph, his second major triumph after the 2016 U.S. Open.
The world number one, who has finished in the top 10 in his past five Masters appearances, set a scoring record with his sensational 20-under 268 for the week back in November.
As Johnson aims to become the first man since Tiger Woods in 2001 and 2002 to win consecutive green jackets, he will start alongside Englishman Westwood and, as is tradition, U.S. Amateur Championship winner Tyler Strafaci.
The groupings and tee times were confirmed on Tuesday, with Johnson's trio going out at 10:30 EDT.
Jordan Spieth, who ended a 1,351-day wait for a PGA Tour victory at the Texas Open last week, will be in the final group to tee off at 14:00 EDT, along with US PGA Championship victor Collin Morikawa and Cameron Smith.
Rory McIlroy's latest bid to become the sixth golfer to claim a career Grand Slam sees him start straight after Johnson at 10:42 EDT.
McIlroy has finished in the top 10 at Augusta in six of his past seven appearances but is famously still waiting for a first victory, while his major drought stands at 22 events.
An intriguing group has the Northern Irishman playing alongside Jon Rahm and Xander Schauffele.
Brooks Koepka will play with Bubba Watson and Viktor Hovland, while Bryson DeChambeau joins Adam Scott and Max Homa.
Justin Thomas has Tony Finau and Louis Oosthuizen for company, Sergio Garcia starts alongside Webb Simpson and Christiaan Bezuidenhout, and Patrick Reed will measure himself against Paul Casey and Daniel Berger.
Phil Mickelson, the man with the most major titles (five) in the field as Woods is absent, will appear alongside Tommy Fleetwood and Scottie Scheffler.
Honorary starters Jack Nicklaus, Gary Player and Lee Elder will get the tournament under way, with twosome Michael Thompson and Hudson Swafford the first competitors involved.
Sesko opts for Leipzig stay over Arsenal, Man Utd move due to progress opportunities
Benjamin Sesko remains certain that staying at RB Leipzig is the "right decision" to develop his career after turning down reported Premier League interest.
Slovenia international Sesko joined Leipzig from RB Salzburg in 2023, scoring 14 league goals last campaign, a tally bettered by only seven players in the German top flight.
That form was said to have attracted Arsenal, Manchester United and Chelsea to the 21-year-old, who instead signed a new five-year contract with the Bundesliga club last month.
Having committed his future to life at the Red Bull Arena, the striker believes Leipzig will provide a platform for his progression.
"I thought it through very well," Sesko said to Nogomania, a Slovenian media outlet. "I believe I made the right decision. I wanted to gain more experience, learn more, and not rush things.
"Leipzig are an excellent club that can provide what I need for the next step. Leipzig's vision is clear; everything is geared towards growth, progress, and high goals. I felt it was right to decide this way."
Sesko's new deal could see him stay with Leipzig until 2029, with Marco Rose boasting one of the world's most exciting prospects up top.
The Leipzig attacker scored from 14 of his 47 shots last season in the league, a conversion rate of 29.8% – the third-best ratio in the 2023-24 Bundesliga among players to have managed at least five goals.
That deadly finishing in front of goal will have Rose excited once more, and Sesko says his boss was key to the decision to stay.
"We talked," Sesko explained. "He told me he wanted me to stay but also said I should decide based on my feelings.
"He said if I felt I needed to move on, I should go, but if not, I should stay. He's an excellent coach who has led many great players.
"I'm glad I decided this way. I did it before the Euro to keep a clear head and focus entirely on the championship."
Simpson appointed first vice captain for 2025 U.S. Ryder Cup team
Keegan Bradley has selected former U.S. Open champion Webb Simpson as his first vice captain for the 2025 U.S. Ryder Cup team.
Simpson, who is a seven-time winner on the PGA Tour, has lost all three of his appearances in the biennial men's golf competition.
The 38-year-old won the U.S. Open in 2012 to secure his first major championship win, and has triumphed in the Presidents Cup on three ocassions.
The United States will look to reclaim the Ryder Cup trophy at Bethpage Black in New York next September, having seen Europe win 10 of the last 14 competitions.
"Webb is someone who I have long admired and respected as a competitor and friend," U.S. captain Bradley said.
"He possesses a wealth of team golf experience and knows what it takes to win.
"Webb will be a valuable member of our leadership team and a trusted resource for me as we prepare for Bethpage Black next September."
"I am honoured to be chosen by Keegan to serve as a vice captain in 2025," Simpson added.
"Competing in three Ryder Cups will forever be among my career highlights.
I have no doubt that Keegan will be a fantastic captain and a tremendous leader, and could not be more excited to get to work as we seek to reclaim the Ryder Cup at Bethpage Black."
The Open: Victorious Schauffele eyes career grand slam
Xander Schauffele set his sights on a career grand slam after a brilliant final round saw him claim victory at The Open on Sunday.
Schauffele managed a six-under 65 through his fourth round at Royal Troon, with a run of four birdies in six holes down the back nine seeing him pull clear.
He finished two strokes ahead of Justin Rose and Billy Horschel, with Thriston Lawrence, Russell Henley and Shane Lowry rounding out the top of the leaderboard.
Having also triumphed at the PGA Championship at Valhalla earlier this year, Schauffele has become the first player since Brooks Koepka in 2018 (U.S. Open and PGA) to win two majors in the same year.
Rory McIlroy was the last player to win those same two tournaments in one year, achieving the feat back in 2014.
Only five players have ever previously won all four majors in their careers – Gene Sarazen, Ben Hogan, Jack Nicklaus, Gary Player and Tiger Woods.
Schauffele is looking to follow in their footsteps in the coming years, telling reporters: "If you look hard enough, you can always find it.
"It's something, when you feel like you need an extra kick in the butt, there's several easy ways to motivate yourself.
"There's still a lot of things that I'd like to do in my career, and this is a very big leap towards that. The fire is still burning, maybe brighter than ever."
Looking at the Claret Jug in his post-tournament press conference, the world number three added: "It's an honour. I've always dreamed of doing it.
"That walk up 18 truly is the coolest with the yellow leaderboards and the fans and the standing ovation. It really is one of the coolest feelings I've ever had in my life."
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