Midfielder Alexis Mac Allister scored the crucial goal which helped return Liverpool to the top of the Premier League and ease any nerves about an early wobble in the title run-in.
Jurgen Klopp’s side were by far the better team against Sheffield United but had to sweat for their 3-1 victory, with a top-class strike from the Argentinian with 14 minutes to go giving them control.
The World Cup winner has become a hugely-influential player in the last few weeks playing in a more advanced position – although he started this game as the holding midfielder before moving forward – and his goal had echoes of Steven Gerrard against Olympiacos in 2005.
Whether it proves to be as significant as the one which paved the way for their Champions League win will only be discovered over the next eight games but in the short term it took Liverpool two points clear of Arsenal and three ahead of Manchester City.
With games running out every victory leaves even less margin for error for their rivals, which was why Mac Allister’s goal, an unstoppable strike into the top corner from the edge of the penalty area, was so important after the chasers had both won on Wednesday.
Darwin Nunez’s 18th of the season – courtesy of a mistake from goalkeeper Ivo Grbic – had given the hosts a 17th-minute lead, only for Conor Bradley’s own goal just after half-time to ratchet up the tension.
The classy Mac Allister, one of the most composed players on the pitch, relieved that and substitute Cody Gakpo’s late effort was an added boost to the goal difference which could yet be crucial.
United have conceded 80 goals this season – more than any other top-flight team, with 14 of those coming in the last four outings.
Their first half was indicative of why they are bottom of the league and destined for a swift return to the Championship as a failure to take gilt-edged chances and an inability to avoid mistakes proved costly.
Sunday’s visitors Brighton scored after 90 seconds but the Blades could have even beaten that when former Liverpool academy graduate Jack Robinson’s long throw was flicked on to James James McAtee at the far post but he shot straight at Caoimhin Kelleher from just a few yards.
Ben Brereton-Diaz then flicked the resulting corner wide and while taking either of those chances may not have been enough for the leakiest side in the top flight it would have at least given them something to cling on to.
Instead they shot themselves in the foot as, after Mohamed Salah had a chip tipped over by Grbic, the United goalkeeper was culpable for the opening goal.
The Croatian dithered too long in clearing a backpass and that was all the invitation Nunez needed to charge him down, with the clearance rebounding off him into an unguarded net.
Mac Allister, Dominik Szoboszlai and Luis Diaz all had attempts, while Ryan Gravenberch showed his lack of recent game time in shooting weakly at Grbic instead of playing in Nunez.
Deep into additional time Jayden Bogle forced Kelleher into a save low down by his left-hand post and it seemed a brief respite until Gus Hamer outjumped Bradley with his header deflecting off the defender and through the legs of Kelleher in the 58th minute.
Andy Robertson and Harvey Elliott, on his 21st birthday, were already stripped to come on before the goal but the departure of leading scorer Mohamed Salah was a surprise, even more so to the Egyptian who did not make eye contact with Klopp as he departed.
However, the tactical adjustment, also made with one eye on Sunday’s trip to Manchester United, worked as the hosts began to find more room down the sides as Virgil van Dijk had a header palmed wide and Bradley volleyed Elliott’s deep cross into the side-netting.
But it was another botched clearance, this time by Anel Ahmedhodzic, which created the winner as the defender’s attempt to hoist the ball clear of his own penalty area deflected off Diaz to fall invitingly for Mac Allister to rifle home his fourth in five games.
Mac Allister the hit the crossbar with a free-kick before Gakpo finished things off in additional time.
Hayes concedes title race is over as Chelsea suffer dramatic Liverpool defeat
It has been a difficult week for Chelsea and their boss Emma Hayes.
After seeing their Champions League dreams dashed by holders Barcelona on Saturday, they had no margin for error when they travelled to Liverpool in the Women's Super League on Wednesday.
Six points behind Manchester City with two games in hand but an inferior goal difference, the Blues needed three points to stop Hayes' final season in charge from totalling unravelling.
But there was to be no respite for the Blues, who were at one point tipped for a quadruple but have been stuck in a downward spiral since losing Sam Kerr to an anterior cruciate ligament injury during the winter break.
Matt Beard's Liverpool put on a tremendous display to win 4-3, with Gemma Bonner scoring a stoppage-time equaliser to leave Hayes certain the title is out of reach.
"I think the title is done," she said after Wednesday's game.
"Of course mathematically it's not, but I think the title is done. Our job between now and the end of the season is to keep pushing until the end, but I think it will be very difficult.
"This team has done a tremendous job in my time here to push for titles.
"I don’t know if we have ever conceded four goals in a half before. Three from set pieces is just unforgivable. But I'm going to credit Liverpool."
Chelsea now need an almighty collapse from City, who may only require three points from their remaining two matches to seal the title, if their goal difference advantage holds firm.
Hayes believes fighting on multiple fronts has not helped her team, adding: "We looked exhausted but I don't want to make excuses.
"I want to remind our fans how much success we have brought over the years. It's just not to be this year."
Next up, Chelsea face relegated Bristol City in their final home game before Hayes departs to take the United States job, with City taking on Arsenal in Sunday's headline fixture.
Sancho outshines Mbappe as Dortmund seize initiative against PSG
Manchester United loanee Jadon Sancho issued a reminder of his star quality as Borussia Dortmund beat Paris Saint-Germain 1-0 in the first leg of their Champions League semi-final tie on Wednesday.
Niclas Fullkrug scored the winner after 36 minutes, taking in Nico Schlotterbeck's floated pass before driving a low shot beyond PSG goalkeeper Gianluigi Donnarumma.
Fullkrug has now been involved in six Champions League goals this season (three goals, three assists), the joint-most by a German player in their debut campaign in the competition, alongside BVB team-mate Marco Reus in 2012-13 (four goals, two assists).
The star of the show, however, was undoubtedly Sancho.
He tormented Nuno Mendes throughout a lively performance, creating three chances for his team-mates – a game-high tally alongside Julian Brandt, Kylian Mbappe and Achraf Hakimi.
Sancho had completed seven dribbles by the halfway point, more than he managed in any full game for the Red Devils.
By full-time, that number had crept up to 12, the most by any player in a Champions League semi-final since Lionel Messi completed 16 for Barcelona against United in April 2008, and the most on record by an Englishman at any stage of the competition (since 2003-04).
Sancho even outshone Mbappe, who struck the far post with a curling effort early in the second half but was limited to just three shots totalling 0.17 expected goals (xG).
PSG did have their chances, though, with their total of 14 shots their most without scoring in any Champions League game since the second leg of their 2020-21 semi-final against Manchester City (also 14), when they were beaten 2-0 and eliminated from the competition.
Dortmund are now unbeaten in 11 straight Champions League home games, winning seven and drawing four.
It's their longest ever such streak at Signal Iduna Park, and they have also won four straight knockout games on their own turf for the first time in their Champions League history.
While Dortmund have a valuable lead to protect in Paris next Tuesday, Edin Terzic will be expecting a strong reaction from PSG.
The Ligue 1 champions have progressed from two of their last four Champions League knockout ties when losing the first leg, with the first of those successes coming against Dortmund in the last 16 in 2019-20 (1-2 away, 2-0 at home).
Borussia Dortmund 1-0 Paris Saint-Germain: Fullkrug hands hosts first-leg win
Niclas Fullkrug fired home a first-half winner as Borussia Dortmund claimed a 1-0 victory over Paris Saint-Germain in the first leg of their Champions League semi-final tie in Germany.
Nico Schlotterbeck floated a pass into Fullkrug's path and the Germany international brought the ball under his spell with a wonderful touch before drilling a low shot past Gianluigi Donnarumma in the 36th minute.
PSG, on the back foot for much of the first half, improved after the break and struck the woodwork twice in a matter of moments just after the restart.
Kylian Mbappe curled an effort against the right-hand post before Achraf Hakimi scuffed a shot against the other upright on the rebound as Edin Terzic's side escaped with a first-leg lead.
The teams will meet again at the Parc des Princes next Tuesday, with the winners of the tie facing either Bayern Munich or Real Madrid – who drew 2-2 in their first leg on Tuesday – in the final at Wembley Stadium.
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