Barcelona remain third in LaLiga after being held to a 0-0 draw by Athletic Bilbao at San Mames.
A frustrating evening for Barca included midfielders Frenkie de Jong and Pedri coming off with injuries in the first half.
Xavi’s men are eight points behind leaders Real Madrid, who had drawn 2-2 at Valencia on Saturday.
And they are a point behind second-placed Girona, whose 1-0 loss at Mallorca earlier on Sunday, via a first-half Jose Manuel Copete goal, had offered Barca the chance to climb the table.
Fourth-placed Atletico Madrid beat Real Betis 2-1 at home with a Rui Silva own goal and Alvaro Morata effort putting the hosts in charge before William Carvalho’s reply, and Alexander Sorloth netted a hat-trick as Villarreal thrashed second-bottom Granada 5-1 at El Madrigal.
In Serie A, second-placed Juventus suffered a third defeat in five games as they lost 2-1 at Napoli.
Giacomo Raspadori scored a late winner on the follow-up when Victor Osimhen’s penalty was saved by Wojciech Szczesny, after Federico Chiesa had cancelled out Khvicha Kvaratskhelia’s opener.
It leaves Juve 12 points adrift of Inter Milan, who host Genoa on Monday.
Fourth-placed Bologna strengthened their Champions League bid by coming from behind to triumph 2-1 at Atalanta, with Scotland’s Lewis Ferguson netting the winner.
Cagliari moved up a place to 18th with a 1-0 win at Empoli. They are level on points with 17th-placed Hellas Verona, who beat Sassuolo 1-0 at home.
Sunday’s other top-flight game in Italy saw Frosinone and Lecce draw 1-1.
Bayer Leverkusen went 10 points clear at the top of the Bundesliga with a 2-0 win at 10-man Cologne.
After the hosts had Jan Thielmann sent off early on, Jeremie Frimpong and Alejandro Grimaldo scored in each half for Xabi Alonso’s men as they took full advantage of second-placed Bayern Munich being held at Freiburg on Friday.
Maximilian Beier’s first-half brace secured a 2-1 win for Hoffenheim at home against Werder Bremen, the hosts holding out for three points after having Marius Bulter sent off in the 73rd minute and conceding a stoppage-time Skelly Alvero goal.
In Ligue 1, Brest are nine points behind Paris St Germain in second after Pierre Lees-Melou’s first-half effort secured a 1-0 home win over Le Havre, extending their unbeaten run to 13 games.
Toulouse came from behind to win 2-1 at home against fifth-placed Nice, and Lens are up to sixth following a 3-0 win at Lyon.
Lorient moved out of the relegation zone with a 2-1 win at Rennes, Montpellier dropped in having drawn 2-2 at home with Strasbourg and second-bottom Metz won 2-0 at Nantes.
Celta Vigo 2-2 Barcelona: Stunning late show denies 10-man Blaugrana
Celta Vigo scored two goals in two minutes late on to earn an entertaining 2-2 draw with Barcelona in LaLiga at the Estadio Abanca-Balaidos.
League leaders Barca appeared to be cruising towards victory when they opened up a two-goal lead thanks to captain Raphinha and leading goalscorer Robert Lewandowski.
Raphinha cut inside before tucking home for the opener 15 minutes in, then Lewandowski got his 15th league goal of the season with a simple finish in the 61st minute.
However, the script changed when Blaugrana midfielder Marc Casado was sent off after receiving his second yellow card in the 82nd minute.
With Barca down to 10 men, the home side piled on the pressure and it told in the 84th minute, substitute Alfonso Gonzalez converting following an error from Jules Kounde.
The comeback was complete two minutes later, with Hugo Alvarez drilling past Inaki Pena to deny Flick's visitors victory.
Despite the result, Barca top LaLiga with 34 points, five ahead of Atletico Madrid in second and seven ahead of third-placed Real Madrid, who have two games in hand.
Data Debrief: Blaugrana finally held
Going into Saturday's game, Barcelona had gone 24 matches without a draw in LaLiga, winning 20 and losing four.
When they entered the final six minutes with a two-goal advantage, it appeared certain they would match their longest streak without a draw in the competition's history, recorded between February and October 2017 (25 games, 23 wins and two draws).
However, Hansi Flick's side were stunned at the death as they dropped points for a second game in succession following a 1-0 loss at Real Sociedad prior to the international break.
'I love where I am,' says Simeone after 700th game in charge of Atletico
Diego Simeone said he is "calm and at peace" at Atletico Madrid after his side edged Deportivo Alaves 2-1 in LaLiga in his 700th game in charge of the club.
Atletico went behind through a Jon Guridi penalty in the seventh minute, but Antoine Griezmann drew them level from the spot in the 76th minute.
The winner came via Alexander Sorloth in the 86th minute as Atletico moved four points behind leaders Barcelona.
Simeone, who has been in charge of Atletico since 2011, is the first coach to manage 700 matches with the same LaLiga club.
"I live in the present, we are having a good time, the boys are working very responsibly," Simeone told DAZN.
"I am calm and at peace. I love where I am and that's it."
He managed Atletico to LaLiga title triumphs in 2014 and 2021 and also helped Los Rojiblancos win two Europa League titles in 2012 and 2018.
The game against Alaves was Simeone's 492nd LaLiga match in charge, and the Argentine has also managed the third-most games with a single club in the Champions League (109), after Alex Ferguson with Manchester United and Arsene Wenger at Arsenal.
AC Milan 0-0 Juventus: Bianconeri maintain unbeaten start after Rossoneri stalemate
AC Milan and Juventus shared the spoils following a dour goalless draw at San Siro.
The Bianconeri maintained their unbeaten start to the Serie A season, but missed the chance to go second behind leaders Inter after a game lacking in quality and chances.
With the likes of Dusan Vlahovic and Arkadiusz Milik out injured, Juventus began the game without a recognised striker, as Teun Koopmeiners and Weston McKennie led the line.
Koopmeiners hit the side-netting from a tight angle after 10 minutes, while Kenan Yildiz grazed the post following a fine individual run midway through the half.
Alvaro Morata had Milan's best chance at the other end, but the former Juventus striker could only head wide from Rafael Leao's free-kick.
Opportunities did not fall as freely in the second half either, and both teams left the field to a chorus of boos on the referee's final whistle.
Data Debrief: Stubborn Juve take clean sheet tally into double figures
Juve are the first team to register 10 clean sheets in their opening 13 matches of a Serie A season since Roma (also 10) in 2013-14.
The Bianconeri have also kept five clean sheets in their first six away league games in a campaign for only the fourth time, also achieving the feat in 1967-68, 2004-05, 2023-24.
Meanwhile, Thiago Motta is only the fifth Juventus manager to go unbeaten in his first 13 league matches in charge (won six, drawn seven), after Jesse Carver, Cestmir Vycpalek, Antonio Conte and Maurizio Sarri.
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