Ilkay Gundogan scored a stoppage-time penalty to give Barcelona a 2-1 win at Las Palmas and close the gap at the top of LaLiga.
After Barca saw defender Joao Cancelo forced off early on with a knee injury, Munir El Haddadi put the Canary Islanders ahead against his former club.
Ferran Torres equalised soon after the restart before Gundogan slotted in a dramatic late winner from the penalty spot after being pushed over by Daley Sinkgraven, who was shown a red card, to leave Barca seven points behind leaders Real Madrid and Girona.
Brazil forward Vitor Roque was named on the bench after Barcelona received league clearance on the 18-year-old forward’s 40million euro (£35m) move from Athletico Paranaense.
There was an early injury worry for Barca when Cancelo was forced off for some treatment on a knee problem. Although the Portugal defender came back on, he did not last long and was replaced by Andreas Christensen.
Las Palmas soon took the lead in the 12th minute when former Barca striker El Haddadi swept in a low cross from fellow Blaugrana old boy Sandro Ramirez.
Barca looked for a swift response as defender Alejandro Balde got clear down the left, but his ball into the penalty area was cleared behind.
Sandro tested Barca keeper Inaki Pena with an angled drive at the near post following another fluid counter attack by the hosts.
Las Palmas continued to press, with Pena first making a smart save from Javier Munoz’s rising drive before Sandro’s deflected effort from the rebound hit the base of the post.
There was a slight delay at the start of the second half as the bottom of the goal net which Barcelona would be attacking needed some repairs.
Barca threatened when Raphinha fired over from the edge of the penalty area.
The equaliser eventually came in the 55th minute when the ball took a couple of fortuitously defections through the Las Palmas penalty area and fell to Torres, who slotted into the bottom corner.
Frenkie De Jong fired straight at Las Palmas goalkeeper Alvaro Valles after being set up by the busy Gundogan.
Barca boss Xavi made a change for the closing 20 minutes, as Robert Lewandowski was replaced by Joao Felix and Lamine Yamal came on for Raphinha.
Las Palmas went close when Mika Marmol glanced a header wide from a corner before Roque was handed his Barca debut in the 79th minute, coming on for Torres.
Just when it looked like Barca would have to settle for a point, Las Palmas substitute Sinkgraven bundled over Gundogan at the far post as the midfielder looked to head the ball in – and was shown a straight red card.
Gundogan picked himself up and took the resulting penalty himself to calmly slot in a stoppage-time winner before Roque stabbed a late chance wide from six yards.
Hayes concedes title race is over as Chelsea suffer dramatic Liverpool defeat
It has been a difficult week for Chelsea and their boss Emma Hayes.
After seeing their Champions League dreams dashed by holders Barcelona on Saturday, they had no margin for error when they travelled to Liverpool in the Women's Super League on Wednesday.
Six points behind Manchester City with two games in hand but an inferior goal difference, the Blues needed three points to stop Hayes' final season in charge from totalling unravelling.
But there was to be no respite for the Blues, who were at one point tipped for a quadruple but have been stuck in a downward spiral since losing Sam Kerr to an anterior cruciate ligament injury during the winter break.
Matt Beard's Liverpool put on a tremendous display to win 4-3, with Gemma Bonner scoring a stoppage-time equaliser to leave Hayes certain the title is out of reach.
"I think the title is done," she said after Wednesday's game.
"Of course mathematically it's not, but I think the title is done. Our job between now and the end of the season is to keep pushing until the end, but I think it will be very difficult.
"This team has done a tremendous job in my time here to push for titles.
"I don’t know if we have ever conceded four goals in a half before. Three from set pieces is just unforgivable. But I'm going to credit Liverpool."
Chelsea now need an almighty collapse from City, who may only require three points from their remaining two matches to seal the title, if their goal difference advantage holds firm.
Hayes believes fighting on multiple fronts has not helped her team, adding: "We looked exhausted but I don't want to make excuses.
"I want to remind our fans how much success we have brought over the years. It's just not to be this year."
Next up, Chelsea face relegated Bristol City in their final home game before Hayes departs to take the United States job, with City taking on Arsenal in Sunday's headline fixture.
Sancho outshines Mbappe as Dortmund seize initiative against PSG
Manchester United loanee Jadon Sancho issued a reminder of his star quality as Borussia Dortmund beat Paris Saint-Germain 1-0 in the first leg of their Champions League semi-final tie on Wednesday.
Niclas Fullkrug scored the winner after 36 minutes, taking in Nico Schlotterbeck's floated pass before driving a low shot beyond PSG goalkeeper Gianluigi Donnarumma.
Fullkrug has now been involved in six Champions League goals this season (three goals, three assists), the joint-most by a German player in their debut campaign in the competition, alongside BVB team-mate Marco Reus in 2012-13 (four goals, two assists).
The star of the show, however, was undoubtedly Sancho.
He tormented Nuno Mendes throughout a lively performance, creating three chances for his team-mates – a game-high tally alongside Julian Brandt, Kylian Mbappe and Achraf Hakimi.
Sancho had completed seven dribbles by the halfway point, more than he managed in any full game for the Red Devils.
By full-time, that number had crept up to 12, the most by any player in a Champions League semi-final since Lionel Messi completed 16 for Barcelona against United in April 2008, and the most on record by an Englishman at any stage of the competition (since 2003-04).
Sancho even outshone Mbappe, who struck the far post with a curling effort early in the second half but was limited to just three shots totalling 0.17 expected goals (xG).
PSG did have their chances, though, with their total of 14 shots their most without scoring in any Champions League game since the second leg of their 2020-21 semi-final against Manchester City (also 14), when they were beaten 2-0 and eliminated from the competition.
Dortmund are now unbeaten in 11 straight Champions League home games, winning seven and drawing four.
It's their longest ever such streak at Signal Iduna Park, and they have also won four straight knockout games on their own turf for the first time in their Champions League history.
While Dortmund have a valuable lead to protect in Paris next Tuesday, Edin Terzic will be expecting a strong reaction from PSG.
The Ligue 1 champions have progressed from two of their last four Champions League knockout ties when losing the first leg, with the first of those successes coming against Dortmund in the last 16 in 2019-20 (1-2 away, 2-0 at home).
Borussia Dortmund 1-0 Paris Saint-Germain: Fullkrug hands hosts first-leg win
Niclas Fullkrug fired home a first-half winner as Borussia Dortmund claimed a 1-0 victory over Paris Saint-Germain in the first leg of their Champions League semi-final tie in Germany.
Nico Schlotterbeck floated a pass into Fullkrug's path and the Germany international brought the ball under his spell with a wonderful touch before drilling a low shot past Gianluigi Donnarumma in the 36th minute.
PSG, on the back foot for much of the first half, improved after the break and struck the woodwork twice in a matter of moments just after the restart.
Kylian Mbappe curled an effort against the right-hand post before Achraf Hakimi scuffed a shot against the other upright on the rebound as Edin Terzic's side escaped with a first-leg lead.
The teams will meet again at the Parc des Princes next Tuesday, with the winners of the tie facing either Bayern Munich or Real Madrid – who drew 2-2 in their first leg on Tuesday – in the final at Wembley Stadium.
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