Xavi said Barcelona had been handed the toughest possible draw after they were paired with Manchester United in the Europa League's knockout round play-offs.
Barca will compete in the Europa League after the turn of the year as a result of their failure to advance from a Champions League group containing Bayern Munich and Inter.
The Blaugrana have now suffered successive group-stage eliminations from the Champions League for just the second time, having also done so under Louis van Gaal in the 1997-98 and 1998-99 campaigns.
Barca were beaten by eventual winners Eintracht Frankfurt in the last eight of the Europa League last term, and Xavi said they had been unfortunate once again following Monday's draw.
"We will have to compete, going to Manchester against a really tough rival," Xavi said ahead of Tuesday's trip to Osasuna in LaLiga.
"It's a historic rival that has grown a lot with the arrival of Erik ten Hag, with great individual players. We have been given the most difficult rival, yet again, in the Europa League.
"There is always a rival who also has the obligation to win, like ourselves. To compete, we have to analyse Manchester. We will try, this club has never won the Europa League.
"It's a massive challenge for us, our players will probably be more motivated against a strong team."
Barca's next European tie will see them reunited with their old foe Cristiano Ronaldo, who has scored 20 goals in 34 games against the Blaugrana, netting against them in LaLiga (nine), the Champions League (two), the Copa del Rey (five) and the Supercopa de Espana (four).
Xavi refuted suggestions the United striker is in decline despite his struggles this season, adding: "He seems to me to be a great player who has marked an era, and he can still make a difference.
"I like to win, I hate to lose, whoever is in front of me. I want to win and be competitive."
Barca have won their last four games against United, including Champions League finals in 2009 and 2011, having won just one of the sides' previous eight meetings in European competitions (D4 L3).
Al Hilal 3-1 Al Fateh: Neves on target as Saudi giants close in on title
Al Hilal moved 12 points clear of Cristiano Ronaldo's Al Nassr at the top of the Saudi Pro League as Ruben Neves scored in a 3-1 win over Al Fateh on Friday.
Former Wolves star Neves slotted in from the penalty spot in the 74th minute, as Al Hilal completed a rapid comeback.
Having fallen behind to Lucas Zelarayan's 57th-minute opener, Al Hilal responded swiftly through Micheal before Salem Al Najdi fouled Mohammed Al Qahtani in the penalty area.
Ex-Barcelona winger Cristian Trello and Al Fateh coach Slaven Bilic were booked for their complaints, with Neves making no mistake, paving the way for Ali Al Bulayhi to seal victory in the 15th minute of an extended period of stoppage time.
Data Debrief
Al Hilal have now won 21 games on the spin in the league. They have scored 86 goals across their 28 matches this season, winning 26 in total.
They had 19 shots on Friday, accumulating 2.34 xG to Al Fateh's 0.25, with pass-master Neves creating three chances to go along with his goal.
Man Utd cannot afford to get complacent – Ten Hag
Erik ten Hag urged his players not to get complacent against a Burnley side who are still fighting for their place in the Premier League.
After a run of four games without a win in the top-flight, Manchester United came from behind with late goals from Bruno Fernandes and Rasmus Hojlund to beat bottom-of-the-table Sheffield United on Wednesday.
The Red Devils sit in sixth place on 53 points, three more than Newcastle United below them, but have not yet secured a place in Europe next season.
When asked what kind of challenge Burnley would pose, Ten Hag was full of praise for the way Vincent Kompany has set up his team.
“They play high-intensity football. They have changed their approach slightly in the season. They have had good results and are hard to beat, and all the compliments to Vincent and his staff.
“We can’t afford to think [it’s only X] about any opponent. With the team we have available, we have to be creative. We have to take every opponent with 100% focus. We can’t allow and do a little bit less.”
Burnley’s survival hopes were given a huge boost last weekend with an impressive 4-1 win against Sheffield United, leaving them just three points behind Nottingham Forest in 17th.
With just four games left of the season, Kompany highlighted the characteristics have kept the Clarets within touching distance of the teams around them.
He said: “The biggest thing is consistency, hard work and making sure to not get distracted by the outside noise has been the main factor. We haven't found the recipe for Champions League football yet, but we are improving every game.
"I know we still have a chance and that's all that matters to me, whether it's two teams, three teams or four teams still in it, it doesn't matter too much to me.”
RFEF elects Rocha as new president
The Spanish Football Federation (RFEF) has confirmed Pedro Rocha as its new president.
Rocha has been elected as Luis Rubiales' replacement, despite being under investigation for corruption.
He had been serving as interim president since Rubiales resigned in September over the scandal caused when he kissed player Jenni Hermoso following Spain's Women's World Cup triumph in August.
In a statement released on Friday, the RFEF said: "Pedro Rocha has today been proclaimed the new president of the Royal Spanish Football Federation (RFEF), after having received the support of the majority of the assembly members of this institution that governs Spanish football.
"The process followed the procedure agreed by the Electoral Commission, which met this morning, and the timetable that was established for these elections."
Rocha has been under investigation since earlier in April, after the RFEF's headquarters was raided by police last month. The Spanish government announced on Thursday that it would be stepping in to oversee the running of the organisation.
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