Liverpool can seal progression to the Champions League last 16 when they play on Wednesday, but Barcelona could see their exit confirmed from Europe's top competition.
Jurgen Klopp's Reds make the trip to face Ajax in Group A knowing they are guaranteed a spot in the Europa League at the very least – and simply avoiding defeat would guarantee their place in the Champions League knockout stages.
It is a more dicey affair for Xavi's Barca, however, as they welcome Bayern Munich to Camp Nou in Group C knowing a loss would spell the end of their journey. Even a win will not be enough if Inter defeat Viktoria Plzen.
Tottenham will hope to keep their noses in front in Group D, with Marseille and Sporting CP just a point behind, while Atletico Madrid have work to do in Group B.
Stats Perform previews Wednesday's eight matches by picking through the Opta data.
Ajax v Liverpool
Ajax have made for generous opponents for Liverpool of late, losing their last three against the Reds in the Champions League. Only Juventus (four, 1997-2004) and Real Madrid (seven, 2010-2019) have previously won four in a row against Ajax in the European Cup or Champions League.
Yet Ajax remain the last Dutch side to achieve a home win against Liverpool, albeit that was back in 1966, with the Premier League side unbeaten in seven subsequent trips to the Netherlands.
Liverpool's countrymen have also made hay, as Ajax have won just one of their last eight home European matches against English teams, beating Manchester City in October 2012.
With or without another strong result, this will be an historic occasion for Liverpool and Klopp, who will match Rafael Benitez's 62 Champions League matches in charge of the Reds, who bring up 150 games in the competition.
Barcelona v Bayern Munich
Needing a win, Barca might have hoped to face any team but Bayern, who have a record three Champions League away wins at the Blaugrana. Along with Juventus and Real Madrid, they are one of three teams to have won more matches at Barca than they have lost.
Home and away, Barca have lost nine of their 12 Champions League matches against Bayern, including the past five in a row.
In fact, if Bayern win again, they will match Madrid's record of 10 wins against a single opponent in the competition – Madrid's dominance coming against Bayern.
Although Bayern are already through, they are seeking a fourth home-and-away double against Barca in a Champions League season (also 1998-99, 2012-13 and 2021-22). Dynamo Kyiv (in 1997-98) are the only other team to beat Barca twice in the same campaign even once.
Tottenham Hotspur v Sporting CP
Sporting won 2-0 against Tottenham in Portugal in what was the sides' first meeting, but they have a dismal record in England, with two victories in 15 attempts away to English sides.
Spurs have won six of their seven home European matches against Portuguese opposition, only losing to Benfica in the 2013-14 Europa League.
Both of Tottenham's wins in this campaign have come at home, where Antonio Conte is bidding to become just the second Spurs coach to win each of his first three at home in the Champions League – after Harry Redknapp.
He and Tottenham will know they must keep their focus early and late; Sporting's last three Champions League goals have come in either the first or last minutes of the match, netting twice in second-half stoppage time in the reverse fixture.
Atletico Madrid v Bayer Leverkusen
Atletico have not lost at home to Leverkusen in their prior four such matches, winning two and drawing two, but the Bundesliga team have started to turn the tide, winning two in a row against them in the Champions League.
That strong home record applies whenever Atletico face German opposition, though, as Borussia Dortmund were the last Bundesliga visitors to win there in 1996. Atleti are unbeaten in 11 since.
Diego Simeone needs his team to rediscover their scoring touch, having gone three without a goal in the Champions League.
That is their worst run under Simeone. Only once in the competition have Atletico gone four without netting, back in 2009 under Abel Resino.
Other fixtures:
Club Brugge v Porto
21 – Club Brugge goalkeeper Simon Mignolet has saved all 21 of the shots on target he has faced in the Champions League this season. He has prevented a competition-leading 4.9 goals, according to expected goals on target data.
4 – Four of Porto's last seven Champions League goals have come from the penalty spot.
Inter v Viktoria Plzen
12 – Inter have scored 12 of their last 14 Champions League goals in the second halves of matches. All three against Barca last time out came after the interval – only the third time an away team has netted three second-half goals at Camp Nou in this competition.
28 – Plzen have averaged just 28 per cent of the possession in the Champions League this season, the lowest average by a team in a single season since Opta data collection began in 2003-04.
Napoli v Rangers
4 – Napoli have won all four of their matches in the Champions League this season and could become the first Italian side to win their opening five games in a single campaign since Juventus in 2004-05.
12 – No goalkeeper has faced more shots on target (29) or conceded more goals (12) than Rangers' Allan McGregor in the Champions League this season. Indeed, he has only kept four clean sheets in 21 appearances in the competition overall.
Eintracht Frankfurt v Marseille
50 – Eintracht Frankfurt's Mario Gotze could make his 50th start in the Champions League in this match. He has been involved in 25 goals in his previous 65 appearances, including 21 in his 49 starts.
3 – Marseille have won their last two games in the Champions League – both against Sporting CP – and will be looking to win three in a row for the first time since October-December 2010, when they won four on the spin under Didier Deschamps.
Title-chasing PSG ready for tough game at Lorient, says boss Luis Enrique
Paris Saint-Germain could secure their third straight Ligue 1 title if they defeat Lorient and Monaco fail to beat Lille – but Luis Enrique is not expecting his struggling opponents to hand them any favours.
If Monaco draw or lose against Lille on Wednesday and PSG win away at 17th-placed Lorient, the Parisians would clinch their record 12th league title.
Luis Enrique's side have an 11-point lead over second-placed Monaco with five matches remaining, and a far superior goal difference having lost just one game.
"It's going to be a very difficult game," Enrique told reporters on Tuesday. "When you're at the bottom of the table, you don't have much to lose.
"Generally, teams at the bottom of the table manage to get unexpected results at the end of the season.
"There's a lot at stake. The possibility of being crowned champions is enough to make you pay attention."
The former Barcelona boss, who moved to the French capital last July, is chasing a possible quadruple after PSG booked a Champions League semi-final berth and a spot in the Coupe de France final. PSG secured the Trophee des Champions title in January.
"It motivates us but for the moment, we only have one title, we have to win the league and keep fighting to win it all. It's a long and winding road ahead," Luis Enrique said.
Luis Enrique once again declined to comment on the future of Kylian Mbappe, Ligue 1's highest scorer for the last five seasons.
France captain Mbappe, 25, has been heavily linked with a move to Spanish giants Real Madrid.
PSG, formed in 1970 via the merger of Paris Football Club and Stade Saint-Germain, have won nine of the last 11 Ligue 1 titles.
Mbappe's frustration lies with their performances in the Champions League, however, a trophy they have never lifted despite huge amounts of investment in the squad.
"When Kylian speaks in public, I'll do the same," Luis Enrique said.
Grant McCann hails ‘outstanding’ response as Doncaster close on play-off spot
Grant McCann was a proud man after Doncaster won 4-1 at Colchester to register a 10th straight victory and move into the play-off places.
Colchester took a ninth-minute lead through Jayden Fevrier, who converted Tom Hopper’s cross at the far post, but remain in relegation danger after Rovers’ emphatic comeback.
Luke Molyneux equalised after collecting Jamie Sterry’s short free-kick and scoring with a low 25-yard shot and Doncaster took a 22nd-minute lead through Harrison Biggins, who netted from close range from Molyneux’s delivery.
Tom Anderson netted a third in the 76th minute at the near post from Hakeeb Adelakun’s pass, and Joe Ironside sealed victory when he converted after Sam Hornby had tipped James Maxwell’s shot onto a post.
A point on the final day against Gillingham will seal a play-off spot regardless of results elsewhere and McCann said: “I’m really proud.
“Obviously conceding early wasn’t ideal for us but the response was outstanding.
“We scored two very good goals, the first one from Mols (Molyneux) and the second one was another very good goal and something we knew could help us in the game, Biggo’s (Biggins) runs from the centre circle in between the posts after good play by Mols.
“In the first half, we were a little bit edgy and it was a little bit even Steven in the game.
“But in the second half, we were really comfortable and scored another couple of really good goals.
“We always play for more goals; we never sit tight and take what we’ve got – that’s just the way we like to go about things.
“We came up against a team that’s obviously down the wrong end of the table and we knew it was going to be tough.”
Fevrier had Colchester on track to secure survival but they go into Saturday’s final game just three points above the drop zone, with their goal difference superior by four over Sutton.
Colchester boss Danny Cowley said: “It was a tough night for us.
“We have the ability to self-harm, to self-destruct, in a game where we let four terrible goals in.
“For 75 minutes, it was 2-1 and they’ve had three shots at goal, two from 30 yards, and somehow they’re winning the game.
“We were 2-1 down at half-time where we felt we shouldn’t have been, as we’d done a lot right.
“We were in total ascendency and they don’t even want to score any more goals, they want to hang onto what they’ve got and we gift them another two goals.
“I’ve just looked back at the goals and they’re very hard to defend.
“We actually played well box to box but you can’t say you’ve played well when we’ve conceded the goals that we have.
“It’s a damaging night and I’m really angry. We just did the basics so poorly.”
Barrow must stick together in quest to secure play-off spot – Pete Wild
Barrow boss Pete Wild stressed his side must stick together to secure a League Two play-off spot on the final day of the season.
The Bluebirds suffered a fifth defeat in a painful six-game winless run with a last-gasp 2-1 loss to Bradford.
It means they have to get a result when they host promoted Mansfield on Saturday.
Bobby Pointon opened the scoring with a great strike in the first half before Kian Spence levelled with a free-kick after the break.
But former on-loan Barrow forward Tyler Smith came off the bench to score a bruising stoppage-time winner against his old club.
And Wild said: “We didn’t do anything with or without the ball. We were frustrated at half-time. I told them ‘we’ve got to have a go and try to get over the line’.
“We played really well second half, had a go, came out fighting and got the goal, but it wasn’t enough.
“We were on the front foot. We kept trying to throw subs on to put impetus into the game and you get hit by a sucker punch at the end.
“We had four chances to clear the ball and that’s been the month hasn’t it. There have been key moments in game, chances and opportunities with the football and we’ve not done that.
“We weren’t getting a glove on them and we had to try and be braver, second half.
“I will never make it about them, it’s about us. We’re all a collective. We will win together and lose together and that’s how we’ve gone through the season.
“What we have to do now is just stick together and try to keep going.
“Across the last four games you have seen glimpses of us, but not enough of us across a full 90 minutes to get over the line.”
The Bantams were indebted to Sheffield-born Smith’s late winner for their fourth-straight win.
Boss Graham Alexander said: “I’m pleased that the players have once again showed character and personality to once again get a win from a game we should never have been drawing anyway.
“We were brilliant in the first half and should have been two or three up. But we weren’t and a good team like Barrow are going to come back into it and have a spell of pressure and momentum.
“Ultimately they got a goal from it. From our perspective it’s a poor one to concede going through the wall.
“Our performance became a bit flat after that. They had real quality and gained chances.
“The subs that came on halted their momentum.
“They were going for it as well and it was going to be (down to) who had that quality to score.
“To be fair to Tyler, he would have been under massive pressure in his own head, but he stuck it in the corner so fair play to him.”
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