Benfica could dump Juventus out of the Champions League, while Paris Saint-Germain and Chelsea are among the other clubs who can seal a round-of-16 spot on Tuesday.
Juve must win at Benfica to have any chance from qualifying from Group H, while a victory will be enough to see the home side through. They can also advance with a point if Maccabi Haifa are unable to beat PSG.
The Ligue 1 champions will be through with a victory at the Parc des Princes or if they draw and Juve fail to win in Lisbon.
Chelsea travel to Salzburg as the Group E leaders and are guaranteed to progress if they win, while the Austrian side also remain in the hunt to qualify. The Premier League club can also go through if they draw and third-placed Milan defeat Dinamo Zagreb, who are bottom but only three points behind the leaders.
Borussia Dortmund will be sure to join Manchester City in getting out of Group G if they secure a home win over Pep Guardiola's side, who could win the pool with a game to spare. Real Madrid are in a similar situation to City, while RB Leipzig bid to join the holders in the knockout stage.
Ahead of another tense night of action, Stats Perform picks out the standout Opta numbers for the eight matches.
Benfica v Juventus
Juve have lost all three of their European matches away at Benfica, with their most recent loss a 2-1 Europa League defeat in 2014.
The Turin giants only have one victory home or away in the seven previous meetings between the two famous clubs, Jurgen Kohler, Dino Baggio and Fabrizio Ravanelli on target in a 3-0 UEFA Cup clash in 1993.
Benfica could qualify for the knockout stage for a second consecutive season, a back-to-back feat they have only previously achieved in the 2015-16 and 2016-17 seasons under Rui Vitoria.
Juve could be eliminated in the group stage of the Champions League for the first time since the 2013-14 season, when Antonio Conte was in charge.
Paris Saint-Germain v Maccabi Haifa
Maccabi are winless in three away European games (including qualifiers) in France, losing two and drawing in a Cup Winners' Cup tie at PSG back in 1998.
PSG have only lost one of their past 32 group stage games at the Parc des Princes in the Champions League (W25 D6), with their lone defeat during that run coming against Manchester United in October 2020 (1-2). They have averaged 2.7 goals per game in those fixtures, scoring 86.
Since Kylian Mbappe's Champions League debut in September 2016, only Robert Lewandowski has been directly involved in more non-penalty goals (55) than the France forward (54 – 34 goals, 20 assists).
Omer Atzili has scored twice for Maccabi in the Champions League this season. The last Israeli player to net more in a single campaign in the competition was Eran Zahav, who scored three for Hapoel Tel Aviv in 2010-11.
Salzburg v Chelsea
Chelsea have only played two away European matches in Austria, losing 1-0 at Weiner Sport-Club in November 1965 in the Fairs Cup and drawing 1-1 against Austria Vienna in November 1994 in the Cup Winners’ Cup.
Salzburg are winless in all seven of their European matches against English teams (D2 L5), failing to beat Blackburn Rovers (D1 L1), Manchester City (L2), Liverpool (L2) and Chelsea (D1).
In-form Chelsea have won back-to-back Champions League games, beating Milan 3-0 at Stamford Bridge and 2-0 at the San Siro. The last time they won three games in a row in the competition by a margin of at least two goals was in October-November 2013.
Salzburg have scored exactly one goal in each of their past seven games in the Champions League – only one team have ever had a longer run of scoring a single goal in the competition, with Olympiacos doing so in 10 in a row in a run ending in November 2005.
Borussia Dortmund v Manchester City
No player has been directly involved in more goals than City's Erling Haaland (five goals) or Dortmund's Jude Bellingham (four goals, one assist) during the group stage this season.
Dortmund have won just one of their five Champions League matches against City (D1 L3), a 1-0 home victory in the 2012-13 group stage.
No full-back has been involved in more sequences of play that have ended in shots (29) or goals (five) thans Joao Cancelo in the Champions League this season. The Portugal international has provided three assists in four games, equalling his season-best tally in a Champions League campaign (three in nine games last season).
If Haaland scores on his return to face his former club, it will be the third time he has scored in five or more consecutive appearances in the Champions League. Only five players have achieved that feat on three occasions – Cristiano Ronaldo (five), Lionel Messi (three), Lewandowski (three), Zlatan Ibrahimovic (three) and Ruud van Nistelrooy (three).
Other fixtures:
RB Leipzig v Real Madrid
13 – Madrid are unbeaten in their past 13 games against German sides in European competition (W9 D4), scoring at least two goals in every game during this run (31 in total).
3 – Leipzig will be looking to win three consecutive Champions League games for just the second time – they won three in a row between February and August 2020, beating Tottenham twice and Atletico Madrid once.
Dinamo Zagreb v Milan
5 – Dinamo have lost all five of their matches against Milan in European competition (including qualifiers). Against no side have they lost more games in their European history (also five v Ajax).
100 – Milan's 100 per cent record against Dinamo – winning five out of five games against them – is their best against any side in Europe.
Sevilla v Copenhagen
29 – The average age of Sevilla's starting line-up in the Champions League this season is 29 years and 73 days, the second-oldest of any side in the competition this term after Rangers (29 years 96 days).
13 – Copenhagen are winless in all 13 of their major European matches against Spanish teams (D5 L8), losing their last three on Spanish soil.
Celtic v Shakhtar Donetsk
7 – Celtic have lost seven of their past eight games in the Champions League (D1) and are looking for their first win in the competition since September 2017 (3-0 v Anderlecht).
0 – Shakhtar have never won a Champions League away match against a British team, losing on eight of their nine total trips. They did avoid defeat in the most recent one, however, drawing 1-1 against Manchester City in November 2019.
Terzic: Dortmund have made up for last season's Bundesliga failure
Borussia Dortmund's 2-0 aggregate win over Paris Saint-Germain made amends for last season's disappointing Bundesliga finale, coach Edin Terzic said.
Dortmund showed great composure to reach their third Champions League final and first since 2013 after Mats Hummels' second-half goal earned a 1-0 victory on the night in Paris on Tuesday.
Terzic went to the Dortmund fans after the game and said he felt he had to make up for last season's failure to win the Bundesliga title after slipping up on the very last day.
"Last season, we lost the championship at home on the last matchday. I'm happy that we can now give something back to the fans," Terzic said, remembering how Bayern Munich snatched the Bundesliga title from Dortmund on goal difference.
"[Going to the fans] was a very emotional moment, a beautiful moment. We wished it for last season's last matchday. But today we could pay something back, keep them dreaming and now we'll do everything to bring the trophy back home," he said.
PSG hit the woodwork four times but failed to find the net as Kylian Mbappe, widely expected to leave at the end of the season, was a shadow of his usual brilliant self.
Dortmund will now meet either 14-time European champions Real Madrid or their Bundesliga rivals Bayern in the June 1 showdown at Wembley.
"Before the first game against PSV, we talked for the first time about how short the journey to London could be," Terzic said.
"Back then, many were still puzzled. We've grown with every game and eventually realised that we could be the team that surprises everyone in the end. Now I'm very happy to be in the final with my team."
Dortmund have played a roller-coaster Bundesliga season and sit in fifth place with two games left.
"That plays no role," Terzic said. "In 2013 when Dortmund were in the Champions League final they were 25 points behind in the league and in 1997 when they won it they were also not doing well.
"The season had highs and lows but our season is still not finished."
'I don't see why we shouldn't win' - BVB hero Hummels bullish ahead of Champions League final
Mats Hummels sees no reason why Borussia Dortmund cannot go on and win the Champions League following their hard-earned semi-final victory over Paris Saint-Germain.
The Black and Yellow are through to the final of Europe's premier club competition for only the third time after sealing a 2-0 aggregate over the reigning Ligue 1 champions, who struck the woodwork six times across both legs.
After Niclas Fullkrug settled last week's first leg at Signal Iduna Park, Hummels' second-half header was the difference in the return at Parc des Princes, where Edin Terzic's side produced another defensive masterclass as they claimed their sixth clean sheet in this season's competition.
Dortmund, who lifted the trophy 27 years ago, will face either Real Madrid or Bayern Munich in the final at Wembley on June 1, and Hummels is confident he and his team-mates can go all the way.
"I've scored far too few Champions League goals in my career, just five," he told DAZN via Uefa.com. "Now is a good time to add to that number.
"Since the second match of the group stage, we've believed that we could prevail in every game - and I don't see why we shouldn't win at Wembley now.
"We remained active today and were able to take so much pace out of the game and atmosphere out of the stadium. That was our recipe for success today."
Hummels was part of the Dortmund side beaten 2-1 by Bayern in their most recent Champions League final appearance in 2013, along with Marco Reus.
The veteran midfielder announced last week that he would be leaving the club at the end of this season, and is thrilled to have one more crack at landing the biggest trophy in European club football.
"[It is] indescribable," he told DAZN. "After more than 10 years, I am in the final with Borussia again. Ousmane [Dembele] and Achraf [Hakimi] brought a tremendous amount of pace, and we suffered a lot.
"How we won the game, no-one will ask tomorrow. Shots against the post won’t matter tomorrow. What counts is that Borussia Dortmund are in the final again. Nobody expected this. It's just incredible."
Meanwhile Terzic, who saw his side surrender the Bundesliga title on the final day of last season, saluted the strides his players have made as the competition has progressed.
"Before the first game against PSV [in the round of 16], we talked for the first time about how short the journey to London could be," he said. "Back then, many were still puzzled. Last season, we lost the championship at home on the last matchday.
"I'm happy that we can now give something back to the fans. We've grown with every game and eventually realised that we could be the team that surprises everyone in the end. Now, I'm very happy to be in the final with my team."
'We weren't efficient' - Marquinhos bemoans PSG profligacy after Champions League exit
Marquinhos believes Paris Saint-Germain paid for their profligacy after suffering Champions League semi-final heartbreak against Borussia Dortmund.
Mats Hummels' second-half header from a Julian Brandt corner - the only goal at Parc des Princes - wrapped up a 2-0 aggregate victory for the Bundesliga side, who advanced to their third final and first since 2013.
Meanwhile, PSG's wait to land the elusive European crown goes on, despite a whopping 44 shots across the two legs, while they also struck the woodwork on six occasions - their overall tally of 14 the most recorded by a team during a single campaign.
Indeed, Luis Enrique's side failed to find the net in a home match for the first time since their 0-0 draw with Lorient in their first Ligue 1 match of the season, as their hopes of completing the treble vanished for another year.
"We lacked efficiency," Marquinhos told Canal+. "They scored two goals from corners and a through ball that we had worked on. We had to defend better. These are small details.
"We created chances, a lot more than them. We weren't efficient. They were efficient, they scored two goals and won both matches."
But despite the disappointment, the PSG skipper urged his team-mates to focus on the positives from their run to the semi-finals.
They recovered from a disappointing 4-1 defeat against Newcastle United to finish second behind Dortmund in Group F, before overturning a 4-2 aggregate deficit to deny Barcelona in the quarter-finals.
"There are a lot of things to take away from this competition," Marquinhos added. "At the beginning of the season, no one believed that we would get this far. We've overcome a lot of obstacles, we shouldn't throw everything away now just because we're eliminated.
"You have to remember that it's a new team, with a new coach. There are some positives to bring back for next season. We wanted to go to Wembley for the fans and our families.
"You have to stay calm after the elimination. It's very hard. We've come very close. We had to win tonight and be more efficient."
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