Liverpool face Rangers in a battle of Britain and Barcelona will attempt to apply more pressure on Inter boss Simone Inzaghi with a Champions League victory on Tuesday.
An army of Gers fans will travel south of the border to descend on Merseyside for a Group A clash that will give them another opportunity to secure a first point, with the Reds in second spot behind Napoli.
Barca moved top of La Liga last weekend and Xavi's side will start their third Group C game level on points with out-of-sorts Inter after losing 2-0 to leaders Bayern Munich last month.
Bayern will be expected to maintain their 100 per cent record at the expense of Viktoria Plzen, and Serie A table-toppers Napoli travel to Ajax looking to continue their brilliant start to the season.
Ahead of another mouthwatering set of matches, Stats Perform trawls through the Opta data to highlight the most noteworthy facts for each contest.
Liverpool v Rangers
This will be the first European meeting between Liverpool and the Glasgow giants in a European competition.
The Gers have only won one of their seven away games in England, that being a 2-1 Champions League victory at Leeds United in November 1992 courtesy of goals from Mark Hateley and Ally McCoist. They have suffered six defeats and drawn twice.
Liverpool's last meeting with Scottish opponents in the European Cup was back in the 1980-81 campaign, winning 5-0 on aggregate against Alex Ferguson's Aberdeen (1-0 away, 4-0 home). The Reds went on to win the competition that year.
Jurgen Klopp's side have won 13 of their past 15 home Champions League group stage matches (D1 L1), scoring 36 goals in process. Their solitary defeat was against Atalanta in November 2020
Rangers have failed to score in their two group games so far. Indeed, only Plzen (2) and Sevilla (3) have had fewer shots on target than the Scottish club (4) in this season's first two matchdays.
Inter v Barcelona
Inter have won just two of their 14 European matches against Barcelona (D4 L8), a 2-1 victory in the Inter-Cities Fairs Cup in January 1970 and 3-1 Champions League triumph in April 2010.
Barca's two away wins against the Nerazzurri came 60 years apart, winning 4-2 in the Fairs Cup in September 1959 and 2-1 in the Champions League in December 2019.
Inter have lost six UEFA Champions League matches against the Catalan giants, their most against a single opponent. Barca have only beaten Celtic (8) more times in the competition.
Barca have lost three of their past four away Champions League group stage matches (W1), as many as in their previous 25 matches on their travels in the competition (W15 D7). Xavi is only the second manager to lose his first two away Champions League matches in charge of Barcelona, along with Louis van Gaal in 1997.
Inter have lost their past two Champions League games at San Siro (0-2 v Liverpool and Bayern). Only once previously have they suffered three consecutive home defeats in the European Cup/UEFA Champions League (a run of three between February-September 2011).
Bayern Munich v Viktoria Plzen
Bayern have won all four of their European matches against Plzen, beating them twice in the 1971-72 Cup Winners' Cup and the Champions League in 2013-14.
Plzen's two away European matches against Bayern have seen them concede at least five goals on each occasion, losing 6-1 in September 1971 in the Cup Winners' Cup and 5-0 in the Champions League nine years ago.
Bayern are out to record three wins at the start of a Champions League campaign for a fourth consecutive season. In their opening three games in the previous three seasons and their two games this year, they have won all 11 matches by an aggregate score of 41-7.
Plzen have conceded seven goals in their two Champions League games this season and only kept one clean sheet in their 20 matches in the competition.
Leroy Sane has been directly involved in 14 goals in his past 11 Champions League starts for Bayern (8 goals, 6 assists). The winger could become only the second player to score in Bayern's first three Champions League games in a season, with Robert Lewandowski (in 2019-20 and 2021-22) being the other.
Ajax v Napoli
Napoli have never won away from home in the Netherlands (D2 L3) in any European competition.
Ajax have failed to win any of their past 11 home European matches against Italian opposition (D6 L5) since winning 2-1 against Roma in this competition in December 2002.
Napoli will be looking to win their first three Champions League group stage games for the first time. They are unbeaten in eight matches in the group stage of the competition (W5 D3).
Ajax have won their past four home games in the group stage of the Champions League, scoring four goals in each of the previous three (4-0 v Borussia Dortmund, 4-2 v Sporting CP and 4-0 v Rangers).
Napoli are the top scoring side in the Champions League this season with seven goals. Luciano Spalletti's side have had more shots (43) and shots on target (19) than any other team.
Other fixtures:
Marseille v Sporting CP
6 - Marseille have lost six of their eight European Cup/Champions League matches against Portuguese opponents (W1 D1).
16 - Marseille have lost 16 of their past 17 Champions League matches (W1), failing to score in 11 matches in this run, including both games this season.
Porto v Bayer Leverkusen
7 - Porto have won seven of their eight home Champions League games against German opposition (D1), winning five in a row.
2 - Leverkusen have only won two of their past 13 away matches in the Champions League (D5 L6), with three of the previous four ending in defeats without scoring.
Club Brugge v Atletico Madrid
3 - Brugge are unbeaten in all three home meetings with Atleti in European competition (W2 D1).
7 - Atleti have never won a European match against a Belgium club in seven attempts (five away, two neutral). They have played more major European games on Belgian soil without winning than in any other country.
Eintracht Frankfurt v Tottenham
4 - Tottenham have lost their past four Champions League matches against German opposition by an aggregate score of 14-3, losing twice to Bayern Munich (2-7 and 1-3) and twice to RB Leipzig (0-1 and 0-3).
3 - Eintracht have won three consecutive European games against English teams (one versus Arsenal, two v West Ham), as many as in their first 14.
Sessegnon rejoins boyhood club Fulham after Tottenham departure
Ryan Sessegnon has resigned for Fulham on a free transfer, five years after leaving the club.
The 24-year-old signed a two-year contract with the Cottagers with the option to extend for a further year following his departure from Tottenham last month.
In his first spell at the club, Sessegnon worked his way through the academy over 11 years, scoring 25 goals in 120 first-team appearances.
He then moved to Spurs in a £25million deal in 2019, though struggled to nail down a place in North London, making just 57 appearances in all competitions, and scoring three goals.
"It's amazing to be back. Emotional, as well," he told FFCtv. "It's where it started for me, where everything began, and it's amazing to be back.
"It will always be home for me. I think it had the feeling that it was meant to be, coming back here, so I'm delighted to get it done."
Sessegnon is Fulham's first signing of the transfer window, though they have seen plenty of first-team departures already, with Joao Palhinha, Tosin Adarabioyo and Bobby De Cordova-Reid all leaving the club.
Slot's Liverpool success will be measured by trophies, says McAllister
Gary McAllister says Arne Slot must be prepared to aim high by targeting trophies if he is to be successful with Liverpool.
The Dutchman is set to begin his first season in charge of the Reds after being appointed as Jurgen Klopp's successor in May.
Liverpool enjoyed a trophy-laden spell under the German, winning their first-ever Premier League title, as well as a Champions League, a Club World Cup, a Super Cup, an FA Cup and two EFL Cups.
However, Slot was no stranger to success while at Feyenoord, leading the team to the Eredivisie title in 2022-23 before lifting the KNVB Cup in April during his final season with the club.
McAllister, who won five trophies in the two years he spent at Liverpool, says Slot's success will be determined by the silverware he collects.
"Liverpool is a club that's synonymous with winning, and when you don't win you fail," McAllister told Stats Perform.
"When there's a new management team, you're given a little bit more time, but the facts are Liverpool's target, I felt, and as a player that played against them for most of his career, the targets that Liverpool set, you go into every tournament looking to win it.
"You try to win every game and that's the expectation of the club and that's what makes it a very special club."
Klopp spent nine years at Liverpool, breaking club records as his team pushed for trophies on a regular basis.
The Reds enjoyed a club-record 68-match unbeaten run at Anfield over nearly four years in the Premier League between April 2017 and January 2021.
Klopp also oversaw three of the four most prolific seasons in Liverpool's history, including the club-record total of 147 goals scored in 2021-22.
Slot has admitted he has "big shoes to fill", but McAllister believes the 45-year-old will be able to live up to the high expectations left behind by Klopp.
"Arne arriving at the club, following Klopp, realising that it's such a difficult job anyway, but to follow somebody who's done particularly well at the club over an eight, nine-year period is going to be tough, and I don't think the new manager is under any illusions," he added.
"What I would say is he's a man that seems to be a very strong character, good personality, and he's just got to come in and be his own man and trust what he does.
"He's done very well in his previous managerial career and coming to Liverpool I feel is a natural progression in the levels of the game that he's worked at.
"So, everybody at the club will be deeply backing him and be right behind him, he'll have amazing support."
Liverpool's first pre-season game under Slot ended in a 1-0 defeat to Preston North End last week before the players flew out to the United States for a three-game tour.
They are also only one of two Premier League clubs yet to conduct any business in the transfer window so far, but McAllister urged fans to be patient with Slot while he gets settled in his new role.
"Whenever there's a change at a club, I think the fans have got to realise that it does take time for a new manager, a new coaching group to come in and get their ideas over to the players," he said.
"There's got to be a modicum of patience, but at Liverpool, expectation levels are very, very high and sometimes, in professional soccer, in elite soccer, patience is something that most managers don't get.
"As much as the fans have got to be aware that everything is new and there are new ideas, Arne and the players will want to get off to a quick start.
"I feel that this pre-season tour is going to help them start the season against Ipswich Town very strongly. I feel the games that they've got here in the US, here in Pittsburgh against Betis, and then we go to play Arsenal and Manchester United, the build-up is pretty good."
Jones 'happiest he's ever been' at Liverpool under Slot
Curtis Jones says he is "probably the happiest he's been" since Arne Slot's arrival at Liverpool.
Jones was first promoted to the first team by Jurgen Klopp in September 2019, but despite going on to make 133 appearances for his boyhood club, he failed to nail down a place in the German's starting line-up after that.
Last season, the 23-year-old made 36 appearances in all competitions, more than in any other season, netting five goals as Liverpool won the EFL Cup and finished third in the Premier League.
Now, with a new manager at the helm, Jones believes Slot's more patient approach will suit him better, allowing him to secure a regular starting spot.
"[Slot's] amazing. It's probably the happiest I've been," Jones told reporters during their pre-season camp.
"As a style of play, it suits me. It is a clear plan. Arne is fully involved in the training, he coaches us a lot, he's big on the finer details.
"He knows it's going to take a bit of time because it's a big change. I came around the team as a young lad. I always had a way of playing, but I had to adapt and change.
"It wasn't anything I couldn't do. But this now is more me. I can get on the ball more. I can 'do me' more.
"My way of playing has always been to get on the ball and play, help the team, and be comfortable on the ball.
"I then came around a team who had world-class lads on the wing and up front. The centre-mids were always more like runners, more disciplined.
"Now the midfielders are going to be the heart of the team. In terms of our build-up, we have to be more calm and play more as a team.
"We're not in a rush to attack. We want to have the ball and just break teams down. In the past, it was kind of a rush. It was a bit too direct; it was up and down. Now Arne wants us to have all the ball and completely kill teams."
Liverpool are in the United States for their three-game pre-season tour, starting with Real Betis on Friday.
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