Manchester United forward Russo was named player of the year, while midfielder Walsh, her fellow Euro 2022 winner who joined Barcelona from Manchester City last summer for a world-record fee, took the international player of the year award.
Chelsea forward James and Liverpool midfielder Missy Bo Kearns, both 21, were winners in the young player of the year category.
There were also gongs for two members of the England men’s team, with captain Harry Kane and Declan Rice receiving ally awards, and former England and Arsenal striker Ian Wright was named women’s football champion of the year.
The ceremony, hosted by Eni Aluko and Jamie Carragher, followed more than 20,000 public votes being cast and ratification by a judging panel led by United forward Nikita Parris, Real Madrid midfielder Caroline Weir and Sky Sports News presenter Hayley McQueen.
United, who this season have secured their highest Women’s Super League points haul and Champions League qualification for the first time, as well as making their Women’s FA Cup final debut, were named best club of the year.
Other individuals recognised included former Everton and Liverpool player Fern Whelan, the first women’s football equality, diversity and inclusion executive for the Professional Footballers’ Association, receiving the Off The Pitch award.
Karen Carney, who retired in 2019 with 144 England caps, was honoured with a lifetime achievement award, and there was a special recognition award given to Carol Thomas, the captain of the Lionesses team that were runners-up at the first women’s European Championship in 1984.
Aluko, another former player to have won more than 100 England caps, said: “Tonight was a highlight of my career. This was a first for women’s football and a landmark moment for the game. I am so proud to be part of this event.
“For the first time, women’s football has got the recognition it deserved. It is even more special because the public nominated and voted for these awards.
“To see so many amazing footballers, people, organisations and brands recognised for advancing and improving the game we love was phenomenal.”
Daly’s Lionesses team-mate Lauren James and Arsenal’s Bukayo Saka have been named as the PFA young players of the year in the awards voted for by their peers.
Daly and James were key performers for England in their run to the World Cup final earlier this month, but the accolades they received at the PFA’s 50th anniversary awards event in Salford are based on their performances last season.
Saka was voted the men’s Young Player of the Year after a terrific season for club and country, while a star of the club’s past, Ian Wright, picked up the men’s PFA Merit award.
Jill Scott, who won 161 caps for England and retired after the Lionesses won the Euros last summer, received the women’s Merit award.
Daly’s victory in the senior women’s player category came after she hit 22 goals in the Women’s Super League for Aston Villa last season – a remarkable achievement for a player who featured at left-back in the Lionesses’ successful Euros campaign last summer.
The 31-year-old from Harrogate saw off competition from five other illustrious WSL names on the nominees list – Sam Kerr, Frida Maanum, Guro Reiten, Khadija ‘Bunny’ Shaw and Ona Batlle.
James, who featured in the World Cup final as a substitute after a red card in the last 16 against Nigeria meant she was suspended for the quarter-final and semi-final, was a key player for Chelsea as they won the domestic double.
Haaland enjoyed a stunning debut season for Manchester City, hitting 52 goals in all competitions as they won the Premier League, FA Cup and Champions League treble last season.
The 23-year-old was voted as the Premier League’s top player, seeing off competition from his team-mates John Stones and Kevin De Bruyne, as well as from Arsenal duo Saka and Martin Odegaard and former Tottenham striker Harry Kane, now at Bayern Munich.
Saka secured the young player prize after enjoying his finest season to date, scoring 14 goals for the Gunners and contributing 11 assists.
He was also one of England’s star performers at the World Cup in Qatar last winter.
Wright’s career in football was recognised with the Merit award. The 59-year-old, who starred as a striker for Arsenal, Crystal Palace and England, is now a popular broadcaster for the BBC and ITV.
Wright has become a vocal ally for the women’s game and also campaigns against discrimination within the sport. He became an OBE for services to football and charity in the King’s Birthday Honours in June.
Scott received the women’s merit award in recognition of a stellar career at club and international level. The 36-year-old played for Sunderland, Everton and Manchester City between 2004 and 2022. As well as her England caps, she also featured for Team GB at London 2012 and again in Tokyo in the summer of 2021.
To mark the awards reaching a half-century, the PFA also handed out individual player prizes for the Championship, League One and League Two for the first time.
Chuba Akpom was voted as the second tier’s top player, after top scoring with 28 goals for Middlesbrough. His fine form at Boro earned him a summer move to Dutch side Ajax.
Conor Chaplin, whose 26 goals spearheaded Ipswich’s promotion push from League One, won that division’s award, while Bradford’s Andy Cook was League Two’s Players’ Player of the Year.
