Luke Cowan-Dickie will end his England career after the Rugby World Cup next year by joining Top 14 heavyweights Montpellier.
The hooker, who has won 42 England caps and three for the British and Irish Lions, will end his 12-year spell with Exeter Chiefs to move to France at the end of the season.
Cowan-Dickie follows his Exeter team-mate Sam Simmonds in making the switch from Sandy Park to Montpellier.
"It's gutting to be leaving," said the 29-year-old, who has made 163 appearances for the Chiefs.
"I've been at the Chiefs for 12 years and it's all I've known. That said, this opportunity came up and it was one that I had to think long and hard about. I spoke a lot with my family about it and it wasn't an easy decision to make in the end.
"Obviously, it's a different competition, a different language – which I'll have to learn – but I think it's time for a change.
"Hopefully, I've still got plenty of years left in my career, but this is an opportunity for me to go over there and show what I am all about."
Fellow England international Joe Marchant has also joined the exodus of Premiership players to France, the centre opting to join Stade Francais next season from Harlequins.