Liverpool can seal progression to the Champions League last 16 when they play on Wednesday, but Barcelona could see their exit confirmed from Europe's top competition.
Jurgen Klopp's Reds make the trip to face Ajax in Group A knowing they are guaranteed a spot in the Europa League at the very least – and simply avoiding defeat would guarantee their place in the Champions League knockout stages.
It is a more dicey affair for Xavi's Barca, however, as they welcome Bayern Munich to Camp Nou in Group C knowing a loss would spell the end of their journey. Even a win will not be enough if Inter defeat Viktoria Plzen.
Tottenham will hope to keep their noses in front in Group D, with Marseille and Sporting CP just a point behind, while Atletico Madrid have work to do in Group B.
Stats Perform previews Wednesday's eight matches by picking through the Opta data.
Ajax v Liverpool
Ajax have made for generous opponents for Liverpool of late, losing their last three against the Reds in the Champions League. Only Juventus (four, 1997-2004) and Real Madrid (seven, 2010-2019) have previously won four in a row against Ajax in the European Cup or Champions League.
Yet Ajax remain the last Dutch side to achieve a home win against Liverpool, albeit that was back in 1966, with the Premier League side unbeaten in seven subsequent trips to the Netherlands.
Liverpool's countrymen have also made hay, as Ajax have won just one of their last eight home European matches against English teams, beating Manchester City in October 2012.
With or without another strong result, this will be an historic occasion for Liverpool and Klopp, who will match Rafael Benitez's 62 Champions League matches in charge of the Reds, who bring up 150 games in the competition.
Barcelona v Bayern Munich
Needing a win, Barca might have hoped to face any team but Bayern, who have a record three Champions League away wins at the Blaugrana. Along with Juventus and Real Madrid, they are one of three teams to have won more matches at Barca than they have lost.
Home and away, Barca have lost nine of their 12 Champions League matches against Bayern, including the past five in a row.
In fact, if Bayern win again, they will match Madrid's record of 10 wins against a single opponent in the competition – Madrid's dominance coming against Bayern.
Although Bayern are already through, they are seeking a fourth home-and-away double against Barca in a Champions League season (also 1998-99, 2012-13 and 2021-22). Dynamo Kyiv (in 1997-98) are the only other team to beat Barca twice in the same campaign even once.
Tottenham Hotspur v Sporting CP
Sporting won 2-0 against Tottenham in Portugal in what was the sides' first meeting, but they have a dismal record in England, with two victories in 15 attempts away to English sides.
Spurs have won six of their seven home European matches against Portuguese opposition, only losing to Benfica in the 2013-14 Europa League.
Both of Tottenham's wins in this campaign have come at home, where Antonio Conte is bidding to become just the second Spurs coach to win each of his first three at home in the Champions League – after Harry Redknapp.
He and Tottenham will know they must keep their focus early and late; Sporting's last three Champions League goals have come in either the first or last minutes of the match, netting twice in second-half stoppage time in the reverse fixture.
Atletico Madrid v Bayer Leverkusen
Atletico have not lost at home to Leverkusen in their prior four such matches, winning two and drawing two, but the Bundesliga team have started to turn the tide, winning two in a row against them in the Champions League.
That strong home record applies whenever Atletico face German opposition, though, as Borussia Dortmund were the last Bundesliga visitors to win there in 1996. Atleti are unbeaten in 11 since.
Diego Simeone needs his team to rediscover their scoring touch, having gone three without a goal in the Champions League.
That is their worst run under Simeone. Only once in the competition have Atletico gone four without netting, back in 2009 under Abel Resino.
Other fixtures:
Club Brugge v Porto
21 – Club Brugge goalkeeper Simon Mignolet has saved all 21 of the shots on target he has faced in the Champions League this season. He has prevented a competition-leading 4.9 goals, according to expected goals on target data.
4 – Four of Porto's last seven Champions League goals have come from the penalty spot.
Inter v Viktoria Plzen
12 – Inter have scored 12 of their last 14 Champions League goals in the second halves of matches. All three against Barca last time out came after the interval – only the third time an away team has netted three second-half goals at Camp Nou in this competition.
28 – Plzen have averaged just 28 per cent of the possession in the Champions League this season, the lowest average by a team in a single season since Opta data collection began in 2003-04.
Napoli v Rangers
4 – Napoli have won all four of their matches in the Champions League this season and could become the first Italian side to win their opening five games in a single campaign since Juventus in 2004-05.
12 – No goalkeeper has faced more shots on target (29) or conceded more goals (12) than Rangers' Allan McGregor in the Champions League this season. Indeed, he has only kept four clean sheets in 21 appearances in the competition overall.
Eintracht Frankfurt v Marseille
50 – Eintracht Frankfurt's Mario Gotze could make his 50th start in the Champions League in this match. He has been involved in 25 goals in his previous 65 appearances, including 21 in his 49 starts.
3 – Marseille have won their last two games in the Champions League – both against Sporting CP – and will be looking to win three in a row for the first time since October-December 2010, when they won four on the spin under Didier Deschamps.
Klopp laments late lapse as Liverpool fail to see out win
Jurgen Klopp was lamented his side's late mistake as Liverpool gave up a two-goal lead to draw 3-3 with Aston Villa in the Premier League on Monday.
The Reds were on top after a quick start as Emiliano Martinez gifted them an opener inside the first 61 seconds. Though Youri Tielemans equalised for Villa, Cody Gakpo and Jarell Quansah put Liverpool back in control.
Jhon Duran scored twice late on, netting in the 85th and 88th minutes to deny Klopp’s side three points.
Speaking to Sky Sports after the game, the German admitted that though they could not see out the win, he was proud of his team’s performance.
He said: "It got away from us. We played really good football. We were really good, played a lot of good stuff and caused a lot of problems.
"Before we changed, we gave them too many chances. It was very intense for the boys. They created too much. They were too often in our box, and we made the changes. Then we made a mistake. It happens but in that moment, it opens the door.
"They scored an equaliser, and I don't even know how. The character from the boys tonight was outstanding in our situation. We wanted to win the game. In the moment, when we gave away the 3-2, that was really tricky. That's it, that's the story of the game."
It looked like Quansah’s goal would be the winner for much of the second half, with the young defender heading in his first goal for Liverpool.
"I've been waiting for that moment," he told the BBC. "I don't score too many goals, so when it goes in the back of the net you just saw the emotion come out I guess.
"I just tried to get the best contact on it as I could. I'm thankful it went in.
"The way the crowd celebrated was a surreal moment, definitely one I'll never forget."
Emery praises 'special' Duran in Villa comeback
Unai Emery has praised "special" Jhon Duran after his late brace secured Aston Villa a point in a thrilling 3-3 draw with Liverpool in the Premier League on Monday.
The Reds looked to be on their way to a 3-1 despite Youri Tielemans’ strike after Cody Gakpo and Jarell Quansah added to Emiliano Martinez’s early own goal.
However, Duran's 79th-minute introduction changed the game as the Colombian scored twice in three minutes to salvage a draw.
Villa needed a win to secure a Champions League spot, but a point keeps their fate in their own hands despite Tottenham having a game in hand against Manchester City on Tuesday.
Emery was full of praise for his forward, acknowledging how important his goals could be by Sunday.
Speaking to Sky Sports, he said: "Jhon Duran is a special player. We have to try and help him. He is a good guy, and he needs a team behind him. He is getting our demands better. He was very clinical and today was important for him.
"Today we are celebrating with our supporters, we have to push it and keep working and be consistent. We were consistent all the season. The team was being mature and always consistent in our mind. Inch by inch we did it.
"We are very proud of the season. It is not enough at the moment to get fourth. Even after we scored the two goals, we had chances. We are celebrating the season here with our supporters in Villa Park.
"We are only thinking of us. We will prepare for our match on Sunday, everything is in our hands."
Villa were on a three-game losing run going into the Liverpool contest, and John McGinn highlighted the team’s strong mentality to avoid another defeat.
"It's a brilliant effort towards the end. We got a bit of luck. It's been a tough few weeks with lads coming back and playing through the pain barrier. This place got us going," he told Sky Sports after the game.
"There's some of us that have never been close to the Champions League in our life. The manager has a no-excuse mentality. People have written us off and we've floated under the radar. We'll have our Man City tops on tomorrow.
"Big Jhon [Duran] is a bit nuts and is a nightmare to have in your team, but he's got quality. We need to keep his feet on the ground over the next couple of days."
Barcelona 2-0 Real Sociedad: Blaugrana back to winning ways to reclaim second spot
Barcelona reclaimed second place in LaLiga with a 2-0 home win over Real Sociedad on Monday courtesy of a Lamine Yamal first-half strike and a late Raphinha penalty.
Yamal put Barcelona ahead in the 40th minute when he coolly slotted home from Ilkay Gundogan's pass after a quick breakaway for his fifth LaLiga goal this season.
Raphinha's penalty in stoppage time sealed victory for the hosts after a VAR review for handball, leaving the Basque side in seventh place with 54 points, one behind Real Betis in the last Europa League spot.
Xavi's side leapfrogged Girona to move on to 76 points, one clear of their Catalan rivals who dropped points in Friday's 2-2 draw at Alaves.
Real Madrid have already secured the league title, sitting on 90 points with three games left.
Data Debrief:
Gundogan got a vital assist for Barcelona's opener, and has been involved in 193 open-play shot-ending sequences in LaLiga this season, more than any other player in the competition.
Barcelona have kept a clean sheet in both games against Real Sociedad in LaLiga 2023-24 (W2), achieving this in a single season of the competition for the first time since 2006-07, when they also beat them twice.
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