Julian Alvarez bagged an extraordinary six goals as River Plate finished off the Copa Libertadores group stage with a win, smashing Alianza Lima 8-1 on Wednesday.

The Manchester City-bound 22-year-old had effectively secured the win for River in their final game in Group F, scoring a brace in the opening 20 minutes, before sealing a first-half hat-trick four minutes from the interval.

His third was the pick of the bunch, too, retreating between the lines to receive the ball before driving low and hard into the bottom corner from just outside the penalty area.

Following Santiago Simon's goal in the 53rd minute, Enzo Gomez arguably topped them all for degree of difficulty, sending the ball into the top corner in the 79th minute before Alvarez rounded out the scoring four minutes later.

Los Millonarios ended the group stage undefeated, claiming 16 points from a possible 18 with the win.

Fortaleza snatch second from Colo Colo

In the other Group F game, Fortaleza took the three points and second spot from Santiago, defeating Colo Colo 4-3.

With both teams even on seven points coming into the final matchday, Los Albos needed the win but started the match in an inadequate fashion, conceding in only the second minute to Silvio Romero.

A Moises double before Yago Pikachu's goal in the 61st minute put Fortaleza in control, despite a brace of own-goals from Brayan Ceballos.

Cerro Porteno scrape through

Olimpia were unable to leapfrog Cerro Porteno in Group G despite claiming a 1-0 win in Asuncion, putting the latter through to the last 16 on goal difference.

El Decano needed to win by two goals or more in this Libertadores edition of the Paraguayan Clasico, trailing the Clausura champions by three points and with an inferior goal difference of one.

Despite an early goal from Fernando Cardozo in the 10th minute, they were unable to break the Azulgrana down and will have to continue in the Copa Sudamericana, finishing third.

Colo Colo were unable to make up ground on River Plate in the Copa Libertadores, playing out a 1-1 draw away to Alianza Lima on Thursday.

The Chilean side translated their early dominance into a goal in the 22nd minute albeit from a dead ball, when Leonardo Gil's corner was flicked on by Maximiliano Falcon, with an unmarked Lucero tapping in at the back post.

The visitors had a chance to double the margin only five minutes later when Pablo Miguez was called for a hand ball in the penalty area, but Lucero hooked his attempt and failed to hit the target.

Alianza made them pay straight out of the interval, equalising in the 46th minute. After some aerial tennis, Hernan Barcos deftly brought the ball down and played through Wilmer Aguirre, who fired past Brayan Cortes.

In what was ultimately a tight second half, Falcon had an opportunity to retake the lead for Colo Colo deep into stoppage time from another corner, but his unmarked header went agonisingly wide.

Although the draw leaves Los Albos only three points behind River Plate in Group C with seven points from four games, Fortaleza sit three points behind in third and can still relegate them to the Copa Sudamericana spot.

River Plate drop points in Brazil

The Colo Colo draw came after River Plate's shock 1-1 stalemate with Fortaleza at the Estadio Castelao.

After conceding only one goal over their opening three victories in Group C, Los Millonarios were down 1-0 in only the fourth minute, with Lucas Crispim setting up Silvio Romero.

Enzo Fernandez equalised 13 minutes later from the penalty spot after Tomas Pochettino was brought down, but despite good chances in the second half, River failed to capitalise and make it four victories from four.

Bragantino deny Velez a first Group C win

Velez Sarsfield's hopes of progressing to the knockout stage were dealt a blow after their 1-1 draw with RB Bragantino.

Veteran Lucas Pratto put El Fortin ahead in the 14th minute with a neat finish from an acute angle, and looked as though they were going to hold out for their first group-stage win in Sao Paulo.

With the goal, Pratto now has the highest active number of goals in the competition, scoring 28 times.

Jose Hurtado equalised for Bragantino in the 84th minute with his first-time volley, keeping them in second with five points and putting Estudiantes in box seat to progress from Group C.

River Plate left it late to claim their third successive win in this season's Copa Libertadores group stage, defeating Colo Colo 2-1 in Santiago.

Matias Suarez and Esequiel Barco scored in the final 10 minutes for the four-time Libertadores winners in an overall cagey 90 minutes at the Monumental David Arellano.

Los Albos had an apparent penalty waved away in first-half injury time, when Paulo Diaz brought down Juan Lucero as he was cutting back onto his right foot to shoot.

Diaz would be prominent again with Matias Suarez breaking the deadlock for River in the 83rd minute, though. The Chile international and former Colo Colo player quickly won back possession before playing through Marcelo Herrera, whose cross was not dealt with, and Suarez was on hand to punish.

Returning from injury, Esequiel Barco played a full match and doubled the margin in the 88th minute, rifling home from just outside the penalty area, before Lucero scored a consolation in the second minute of injury time.

Palmeiras make it three from three

Palmeiras took control of Group A and secured their third win of this season's group stage, with the 2021 Libertadores winners defeating Emelec 3-1 in Guayaquil.

The Verdao have not struggled for goals despite a middling start to the Serie A season, and they opened the scoring in spectacular fashion in the 19th minute. 

Following Mayke's cross-field pass, Rony headed in Wesley's first-time delivery back across the penalty area, with the ball not touching the ground in that sequence.

Gabriel Veron made it 2-0 six minutes later, cutting through the Emelec defence in transition, before calmly slotting home past Pedro Ortiz. Joao Rojas scored for the hosts in the 61st, but Breno Lopes eventually restored the two-goal margin.

Pikachu gets two assists as Fortaleza relieve pressure

In the other Group F result, Fortaleza claimed their first-ever win in the Libertadores, defeating Alianza Lima 2-1 at home on Wednesday.

After two respective defeats to begin their Serie A and Libertadores campaigns, Silvio Romero put Fortaleza ahead five minutes after the restart.

Alianza claimed an equaliser in the 70th minute with Pablo Lavandeira getting on the end of Yordi Vilchez's cross, but Yago Pikachu got his second assist of the night, setting Hercules up for the winner nine minutes later.