Atletico Madrid are hoping to recover from losing to Liverpool on matchday three with a repeat of their Anfield heroics last March.
Paris Saint-Germain and Manchester City will look to take bigger steps towards the last 16, while Real Madrid will go in search of another big win against Shakhtar Donetsk.
Inter can put themselves in a good position to progress, too, although city rivals Milan have got much more of a fight on their hands.
Here are some of the key Opta facts for Wednesday's Champions League matches...
Liverpool v Atletico Madrid: Can Suarez improve rotten recent record?
Atletico were winners at Anfield on their last visit as they claimed a 3-2 victory in the last-16 second leg in March 2020. Indeed, Liverpool have only twice beaten Spanish teams at home in 13 attempts in the European Cup and Champions League.
That said, the Marcos Llorente-inspired game last year was one of only two out of 22 at home that Jurgen Klopp has lost in this competition as Reds manager, while Diego Simeone is chasing what would only be the second instance of a third successive away win in the tournament with Atleti.
Luis Suarez will hope to haunt his old side, although recent history is against him: he's only scored one for Atleti in nine Champions League games, and none from open play. Mohamed Salah, meanwhile, needs one more goal to equal Steven Gerrard as Liverpool's top scorer in the competition at Anfield (14).
Manchester City v Club Brugge: Bad omens for Belgian champions
City's 5-1 triumph in Bruges on matchday three took their tally to six wins in seven European games against Belgian opposition, while Brugge are now without a victory over English teams in 13 attempts dating back to February 1995.
Since Pep Guardiola took charge, City have won 80 per cent (20 out of 25) of home Champions League matches, which is the best record for a coach at a single club in the competition among those to take charge of 20 or more. A first win on English soil for Brugge looks unlikely.
Might this be a chance for Raheem Sterling to impress? The England forward has been directly involved in 24 goals in 27 home Champions League games for City, a tally surpassed only by Sergio Aguero (27).
RB Leipzig v Paris Saint-Germain: Nkunku could outshine Messi
PSG have only lost one of their past nine away games in the group stage, but that defeat was against RB Leipzig last season. It was the only time in the previous seven meetings with French sides that Leipzig emerged victorious.
He might be enduring a difficult time in Ligue 1, but Lionel Messi has managed three goals in three games in Europe for PSG. His double in the reverse fixture was his 34th in the competition, something only Cristiano Ronaldo (37) can better.
However, perhaps the most in-form player in 2021-22 is Leipzig's Christopher Nkunku, who has been involved in the most open-play sequences ending in a goal (six) among Champions League midfielders this season. And he has four goals of his own from the first three matches.
Real Madrid v Shakhtar Donetsk: Another big win on the cards with Benzema
Madrid's 5-0 win over Shakhtar on matchday three means the past five meetings between these teams have seen an average of 4.6 goals scored per game. In fact, Los Blancos have scored 15 times in five Champions League matches against Shakhtar: that average of three per game is their best figure against a side they have faced on at least five occasions, apart from Galatasaray (3.4 per game).
Shakhtar are one of just three sides yet to score in this season's group stage, but with Madrid having lost three of their previous eight home games in the competition, this could be a good opportunity.
They will need to stop Karim Benzema and Vinicius Junior, though: they are the two players with the most involvements in shot-ending sequences in 2021-22 (31 and 34, respectively). Plus, Benzema is on a run of 10 goals in 10 home games in the competition.
Sheriff v Inter: Nothing shot-shy about Inzaghi's men
Inter ended Sheriff's 11-game unbeaten run in Europe last time out and will now look to secure consecutive Champions League victories for the first time since October 2018.
The Nerazzurri have lost just once in their previous five Champions League away matches, but Sheriff are unbeaten in their most recent five European games on home soil, excluding qualifiers. They've also won the past two.
Inter certainly have the variety to break down Sheriff's stubborn defence. Each of their previous 17 away goals in the competition have come from open play, while their 29 shots in the meeting on matchday three were the most by an Italian side in a Champions League game since at least 2003-04.
Other fixtures:
Borussia Dortmund v Ajax
45 – Ajax's 4-0 win over Dortmund last time out was the biggest victory by a Dutch side over a German team in Europe since November 1976, when Feyenoord defeated Kaiserslautern 5-0 in the UEFA Cup.
8 – Sebastien Haller has been directly involved in more Champions League goals this season than any other player (eight – six goals, two assists). Among debutants in the competition since 2003-04, this is the highest such figure over a player's first four appearances and one more than Erling Haaland managed.
Milan v Porto
3 – Milan are one of just four sides this season to have lost all three group games. They are on a five-game losing run in the competition, the worst such streak in their history.
1 – Since scoring four for Chelsea against Sevilla in December 2020, Olivier Giroud has scored only once in 250 minutes of play in the Champions League.
Sporting CP v Besiktas
5 – Paulinho has been directly involved in three of Sporting's five goals (two scored, one assisted) in this season's Champions League. Their last player to manage more goals and assists combined in a single season was Nani in 2014-15 (six).
10 – Michy Batshuayi has attempted 10 shots for Besiktas in the Champions League in 2021-22 without scoring. Over the first three matchdays, only Inter's Lautaro Martinez (12) had more shots without finding the net.
The route to ECL final as West Ham prepare to face Fiorentina in Prague showdown
West Ham face Italian side Fiorentina in the Europa Conference League final in Prague on Wednesday night.
The Hammers are bidding to win a first major trophy since the FA Cup in 1980.
Here, the PA news agency looks back at their route to the final.
Qualifying roundWest Ham’s journey to Prague began on August 18, three Prime Ministers ago, with a home meeting against Danish minnows Viborg.
New Italian striker Gianluca Scamacca, Jarrod Bowen and Michail Antonio scored in a 3-1 first-leg win. Scamacca was on target again, along with Said Benrahma and Tomas Soucek, in the away leg to secure a comprehensive 6-1 aggregate victory.
Group stageThe Hammers were drawn with Romanian side FCSB, Belgium’s Anderlecht and Silkeborg of Denmark in Group B.
They fell behind to FCSB at home in their first match but goals from Bowen, Emerson Palmieri and Antonio earned a 3-1 win and David Moyes’ side went on to breeze into the knockout stages with six wins out of six.
Last 16The travelling fans were rewarded with a trip to sunny Cyprus and a tie against AEK Larnaca.
West Ham were struggling domestically, having just been knocked out of the FA Cup by Manchester United and thumped 4-0 at Brighton in the Premier League, but Antonio’s double settled the away leg and a brace from Bowen helped them to a 4-0 win at home, and 6-0 on aggregate, to keep the European adventure going.
Quarter-finalNext up were another Belgian outfit, Gent, and for the first time in the competition West Ham failed to register a victory, with Danny Ings on target in a 1-1 away draw.
But despite conceding an early goal, the home leg was comfortable thanks to another Antonio double, Lucas Paqueta’s penalty and a stunning solo goal from captain Declan Rice to wrap up a 4-1 win.
Semi-finalDutch dark horses AZ Alkmaar would be no pushovers in the last four having already accounted for Lazio and Anderlecht.
West Ham fell behind at the London Stadium to Tijani Reijnders’ first-half goal but Said Benrahma’s penalty and Antonio’s scrambled effort secured a 2-1 win.
In an edgy second leg, Pablo Fornals raced through to score the only goal in stoppage time to inflict AZ’s first European defeat in 26 matches and send the Hammers through.
Fiorentina focus – a look at West Ham’s Europa Conference League final opponents
West Ham face Fiorentina in the final of the Europa Conference League in Prague on Wednesday night.
Here, the PA news agency shines a spotlight on the Italian outfit.
PedigreeIn qualifying for the showpiece in Prague, Fiorentina became the first team to reach all four finals of the major European competitions. They lost in the European Cup final to Real Madrid in 1957 and won the inaugural Cup Winners’ Cup in 1961 by beating Rangers 4-1 on aggregate in the final. Their last appearance in a European final was a defeat by fierce rivals Juventus in the 1990 UEFA Cup final.
CoachVincenzo Italiano, 45, spent most of his playing career as a midfielder with Verona. As a coach he led Spezia to promotion to Serie A in 2020 and kept them up the following season before moving to Fiorentina, where he guided ‘I Viola’ back into Europe for the first time since 2017.
FormFiorentina have enjoyed a fine end to their league campaign, winning eight, drawing four and losing just two matches since March, securing an eighth-placed finish in Serie A. They also reached the final of the Coppa Italia, where they were narrowly beaten 2-1 by Champions League finalists Inter Milan.
StyleItaliano’s free-flowing side are the top scorers in the Conference League with 36 goals, at an average of just over two-and-a-half per match. Italiano also deploys a high defensive line in a bid to squeeze the opposition and control the tempo of the match while dominating possession.
Key menMorocco World Cup star Sofyan Amrabat could be playing his final match for the Italians amid reported interest from Barcelona and Manchester United. Fellow midfielder Antonin Barak is one of Serie A’s most creative players but could be an injury doubt for the final.
Steph Catley signs new Arsenal deal
Defender Steph Catley has signed a new deal with Arsenal, the Women’s Super League club have announced.
The 29-year-old has made 74 appearances for the north London side since making her August 2020 debut as a substitute in Arsenal’s Champions League quarter-final with Paris St Germain.
Catley scored one goal and provided four assists across 32 appearances for Jonas Eidevall’s side this season and is a centurion for Australia having represented the Matildas at two World Cups and two Olympics.
She said: “It feels amazing – this feels like home. I’ve made some incredible friendships here and when the offer came around I knew exactly what I wanted to do and exactly where I wanted to be.
“I’ve never been happier playing football and I feel like this team is very special – we’re building something special and in the future we’re capable of achieving anything.”
Catley joins Lia Walti and Frida Maanum on a growing list of Arsenal players who have chosen to extend their stay.
Head coach Eidevall said: “I’m delighted Steph has signed a new contract with us. Steph is one of the best defenders in the game and brings so much to this group both on and off the pitch.
“She’s a model professional and has delivered time and again when called upon throughout my time here, so we’re all pleased to say Steph will continue to be a part of Arsenal for years to come.”
Head of women’s football Clare Wheatley added: “It’s great news that Steph has signed a new deal here at Arsenal. Steph is one of the top players in the world in her position and has been such a consistent performer in the time she has been here. She is a key part of this team and we’re delighted to say she will continue to wear the Arsenal colours moving forward.”
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